Local electrochemical deposition of copper from sulfate solution

Original scientific paper

Authors

  • Georgii Vasyliev National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, Ukraine https://orcid.org/0000-0003-4056-5551
  • Viktoria Vorobyova National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, Ukraine https://orcid.org/0000-0001-7479-9140
  • Dmytro Uschapovskiy National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, Ukraine https://orcid.org/0000-0002-2809-2774
  • Olga Linyucheva National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, Ukraine

DOI:

https://doi.org/10.5599/jese.1352

Keywords:

LECD, additive manufacturing, COMSOL, copper plating, throwing power, anodic sludge
Graphical Abstract

Abstract

Local electrochemical deposition is a type of electroplating used to plate metal locally or form metal objects using electrochemical principles at a short distance from the working electrode. In this work, deposition of the copper spot was modelled using COMSOL software and experimentally tested in copper sulfate electrolyte using soluble copper anode. The working capillary diameter was 4 mm and the interelectrode distance was 5 mm. The deposited copper of 100 µm thickness was investigated using the 3D-profilometry technique. The geometry of deposited metal was found to be in good accordance with the COMSOL model. The inclusions of anodic sludge were responsible for the surface inhomogeneity of the deposited copper.

 

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References

C. Korner, International Materials Reviews 61 (2016) 361-377. https://doi.org/10.1080/09506608.2016.1176289

P. Regenfuss, A. Streek, L. Hartwig, S. Klotzer, Th. Brabant, M. Horn, R. Ebert, H. Exner, Rapid Prototyping Journal 13(4) (2007) 204-212. https://doi.org/10.1108/13552540710776151

L. Xinchao, M. Pingmei, A. Sansan, W. Wei, International Journal of Machine Tools and Manufacture 173 (2021) 103848. https://doi.org/10.1016/j.ijmachtools.2021.103848

S. D. Leith, D. T. Schwartz, Journal of Microelectromechanical Systems 8(4) (1999) 384-392. https://doi.org/10.1109/84.809052

A .L. Cohen, U. Frodis, F. G. Tseng, G. Zhang, M. Florian, P. M. Will, Micromachining and Microfabrication Process Technology V 3874 (1999) 236-247. https://doi.org/10.1117/12.361227

A. L. Cohen, G. Zhang, F. G. Tseng, F. Mansfield, U. Frodis, P.M. Will, International Solid Freeform Fabrication Symposium, EFAB: batch production of functional, fully-dense metal parts with micron-scale features, Austin, USA, 1998, p. 161-168. https://doi.org/10.26153/tsw/590

J. D. Madden, S. R. Lafontaine, I.W. Hunter, Sixth International Symposium on Micro Machine and Human Science, Fabrication by electrodeposition: building 3D structures and polymer actuators, Nagoya, Japan, 1995, pp. 77-81. https://doi.org/10.1109/MHS.1995.494221

J. Xu, W. Ren, Z. Lian, P. Yu, H. Yu, The International Journal of Advanced Manufacturing Technology 110 (2020) 1731-1757. https://doi.org/10.1007/s00170-020-05799-5

P. Hanekamp, W. Robl, F.‑M. Matysik, Journal of Applied Electrochemistry 47 (2017) 1305-1312. https://doi.org/10.1007/s10800-017-1124-8

S. Morsali, S. Daryadel, Z. Zhou, A. Behroozfar, D. Qian, M. Minary-Jolandan, Journal of Applied Physics 121 (2017) 024903-024908. https://doi.org/10.1063/1.4973622

H. Fan, Y.P. Zhao, S.K. Wang, Key Engineering Materials 667 (2016) 259-264. https://doi.org/10.4028/www.scientific.net/KEM.667.259

J. Hu, M.F. Yu, Science 329 (2010) 313-316. https://doi.org/10.1126/science.1190496

S. K. Seol, D. Kim, S. Lee, J. H. Kim, W. S. Chang, J. T. Kim, Small 11(32) (2015) 3896-3902. https://doi.org/10.1002/smll.201500177

A. Behroozfar, S. Daryadel, S. R. Morsali, S. Moreno, M. Baniasadi, R. A. Bernal, M. Minary-Jolanda, Advanced Materials 30(4) (2017) 1705107. https://doi.org/10.1002/adma.201705107

P. Liu, Y. Guo, Y. Wu, J. Chen, Y. Yang, Crystals 10(4) (2020) 257. https://doi.org/10.3390/cryst10040257

K. Nakazawa, M. Yoshioka, Y. Mizutani, T. Ushiki, F. Iwata, Microsystem Technologies 26 (2020) 1333-1342. https://doi.org/10.1007/s00542-019-04665-z

G. Ercolano, C. van Nisselroy, T. Merle, J. Vörös, D. Momotenko, W. W. Koelmans, T. Zambelli, Micromachines 11(1) (2020) 6. https://doi.org/10.3390/mi11010006

O. V. Linyucheva, M. I. Donchenko, D. Yu. Ushchapovskiy, M. V. Byk, D. M. Skladanniy, Eastern-European Journal of Enterprise Technologies 6 (2014) 48-55.

https://doi.10.15587/1729-4061.2014.30660

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Published

07-06-2022

How to Cite

Vasyliev, G., Vorobyova, V., Uschapovskiy, D., & Linyucheva, O. (2022). Local electrochemical deposition of copper from sulfate solution: Original scientific paper. Journal of Electrochemical Science and Engineering, 12(3), 557–563. https://doi.org/10.5599/jese.1352

Issue

Section

Electrochemical Engineering