Fe3O4/GO nanocomposite modified glassy carbon electrode as a novel voltammetric sensor for determination of bisphenol A

Original scientific paper

Authors

  • Fariba Beigmoradi Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran https://orcid.org/0000-0002-1153-7394
  • Hadi Beitollahi Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran https://orcid.org/0000-0002-0669-5216

DOI:

https://doi.org/10.5599/jese.1482

Keywords:

water samples, modified electrode, differential pulse voltammetry, high repeatability

Abstract

A new voltammetric sensor is proposed for the determination of bisphenol A, using a glassy carbon electrode (GCE) modified with Fe3O4/graphene oxide (GO) nanocomposite. The modification of the electrode surface was performed by dispersion drop-casting. The electro­chemical behavior of bisphenol A was evaluated by cyclic voltammetry (CV). The oxidation peak was observed during the anodic potential scan at potentials of 0.45 V. Higher anodic peak currents (Ipa) were observed at Fe3O4/GO/GCE modified electrode than at bare GCE. The elec­trochemical determination by differential pulse voltammetry (DPV) revealed a linear response in the concentration range of 1.0×10-7 to 5.0×10-5 M, with a detection limit of 9.0×10-8 M. The proposed method was successfully applied using water samples, with good recoveries.

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14-09-2022

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Electroanalytical chemistry

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