Electrodeposition of the Sb2Se3 thin films on various substrates from the tartaric electrolyte

  • Vusala Asim Majidzade Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagıyev Azerbaijan National Academy of Sciences (ANAS), Baku, AZ1143
  • Akif Shikhan Aliyev Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagıyev Azerbaijan National Academy of Sciences (ANAS), Baku, AZ1143
  • Parvin Haydar Guliyev Nakchivan State University, Nakchivan AR, AZ 7012
  • Dunya Mahammad Babanly Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagıyev Azerbaijan National Academy of Sciences (ANAS), Baku, AZ1143 and French Azerbaijani University (UFAZ), Baku, AZ1010
Keywords: Antimony triselenide, semiconductor, electrochemical deposition, polarization, tartaric acid

Abstract

The present contribution is devoted to the electrochemical deposition of Sb2Se3 thin films from tartrate electrolyte. The study was conducted by potentiodynamic, potentiostatic and galvanostatic methods carried out under different conditions at Pt, Cu and Ni electrodes. The kinetics and mechanism of the electroreduction of antimony and selenite ions in the tartaric acid were studied separately for the electrochemical deposition. Comparison of the obtained polarization curves showed that co-deposition occurs between electroreduction potentials of antimony and selenium, indicating depolarization electrode effect for antimony ions. The influence of electrolyte compo­sition, pH, current density, temperature, etc. has been studied. On the basis of cyclic polarization, X-ray phase and SEM-EDX analyses, it is found that Sb-Se thin films are deposited on Pt and Ni electrodes, but not on Cu electrode. Black, uniform, crystalline and shiny films of the stoichiometric composition of Sb2Se3 compound are deposited on Pt and Ni electrodes within the 338-348 K temperature interval, pH 1.85, current density of 2.5-3.0 A/dm2, and annealing temperature of 703 K. Experiments were carried out using the optimal electrolyte composition containing 0.05 M SbOCl + 0.05 M H2SeO3 + 0.007 M C4H6O6.

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Published
08-12-2019
Section
Electrochemical Science