Inhibition performance of a novel quinoxaline derivative for carbon steel corrosion in 1 M HCl

Original scientific paper

Authors

  • Latifa Chahir Laboratory of Materials, Nanotechnology and Environment, Faculty of Sciences, Mohammed V University in Rabat, Av. Ibn Battouta, P.O. Box. 1014 Agdal-Rabat, Morocco https://orcid.org/0009-0004-1020-1145
  • Fouad Benhiba Laboratory of Materials, Nanotechnology and Environment, Faculty of Sciences, Mohammed V University in Rabat, Av. Ibn Battouta, P.O. Box. 1014 Agdal-Rabat, Morocco and Higher Institute of Nursing Professions and Health Techniques of Agadir Annex Guelmim, Guelmim, Morocco https://orcid.org/0000-0001-9050-7646
  • Nadeem Abad Laboratory of Medicinal Chemistry, Drug Sciences Research Center, Faculty of Medicine and Pharmacy, Mohammed V University, Rabat, Morocco https://orcid.org/0009-0003-9288-4789
  • Hassan Zarrok Laboratory of Advanced Materials and Process Engineering, Faculty of Sciences, Ibn Tofail University, P.O. Box. 133, 14000, Kenitra, Morocco https://orcid.org/0009-0003-6641-0627
  • Ismail Warad Department of Chemistry, AN-Najah National University, P.O. Box 7, Nablus, Palestine https://orcid.org/0000-0001-8853-8961
  • Mousa Al-Noaimi Chemistry Department, Faculty of Science, Kuwait University, P.O. Box 5969, Safat 13060, Kuwait https://orcid.org/0000-0003-3156-6181
  • Driss Benmessaoud Left Laboratoire Interface Matériaux Environnement (LIME), Faculty of Sciences Ain Chock University Hassan II, Casablanca, B.P 5366, Morocco https://orcid.org/0000-0002-8921-7016
  • Mustapha Zertoubi Laboratoire Interface Matériaux Environnement (LIME), Faculty of Sciences Ain Chock University Hassan II, Casablanca, B.P 5366, Morocco https://orcid.org/0000-0002-8517-4653
  • Mustapha Allali Institute of Nursing Professions and Health Techniques Fez, EL Ghassani Hospital, Fez 30000, Morocco https://orcid.org/0000-0001-7264-8314
  • Abdelkbir Bellaouchou Laboratory of Materials, Nanotechnology and Environment, Faculty of Sciences, Mohammed V University in Rabat, Av. Ibn Battouta, P.O. Box. 1014 Agdal-Rabat, Morocco https://orcid.org/0000-0003-2328-2015
  • Youssef Ramli Laboratory of Medicinal Chemistry, Drug Sciences Research Center, Faculty of Medicine and Pharmacy, Mohammed V University, Rabat, Morocco and Mohammed VI Center for Research and Innovation (CM6), Rabat 10000, Morocco https://orcid.org/0000-0002-6885-5692
  • Abdelkader Zarrouk Laboratory of Materials, Nanotechnology and Environment, Mohammed V University, Faculty of Science, 4Av. ibn Battuta, B.P. 1014 Rabat, Morocco https://orcid.org/0000-0002-5495-2125

DOI:

https://doi.org/10.5599/jese.2177

Keywords:

Carbon-iron alloy, organic corrosion inhibitor, weight loss, electrochemical testing, quantum chemical calculations
Graphical Abstract

Abstract

In this work, the effect of a new quinoxaline derivative, 2-phenyl-3-(prop-2-yn-1-yloxy) quinoxaline (PYQX), was evaluated as a corrosion inhibitor for carbon steel (CS) in 1 M HCl electrolyte. Weight loss measurement, atomic absorption spectroscopy, potentio­dynamic polarization, electrochemical impedance spectroscopy, scanning electron microscopy with energy dispersive spectroscopy, and UV-vis spectroscopy were employed to assess the inhibitory activity. The electronic properties of the interaction between the inhibitor molecule and the CS substrate were studied using molecular dynamics (MD) simulation, density functional theory (DFT), and Fukui functions. According to AC impedance experiments, the inhibitor under consideration showed a maximum level of 98.1 % inhibition efficiency at 1 mM and 30 °C. The Langmuir adsorption isotherm model explains the adsorption of PYQX on the CS surface. A slope of 1 denotes a strong molecule-substrate interaction, suggesting that the binding occurs at specific surface locations. To understand the functioning of the adsorption mechanism, various thermodynamic and activation parameters were evaluated. PDP tests demonstrated that PYQX functions as a mixed-type inhibitor. Computational correlations (DFT, MD, and Fukui indices) supported the experimental findings.

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Published

14-05-2024 — Updated on 14-05-2024

How to Cite

Chahir, L., Benhiba, F., Abad, N., Zarrok, H., Warad, I., Al-Noaimi, M., Benmessaoud Left, D., Zertoubi, M., Allali, M., Bellaouchou, A., Ramli, Y., & Zarrouk, A. (2024). Inhibition performance of a novel quinoxaline derivative for carbon steel corrosion in 1 M HCl: Original scientific paper. Journal of Electrochemical Science and Engineering, 14(3), 275–296. https://doi.org/10.5599/jese.2177

Issue

Section

Corrosion

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