Electrochemical and quantum chemical parameters of (-)-(S)-9-flu¬oro-2,3-dihydro-3-methyl-10-(4-methyl-1-pipera-zinyl)-7-oxo-7H-pyrido[1,2,3-de]-1,4-benzoxazine-6-carboxylic acidas anti-corrosive agent for API 5L X-52 steel

  • Fidelis Ebunta Abeng Material and Electrochemistry Research Group, Department of Chemistry, Cross River University of Technology, Calabar P. M. B 1123 and Corrosion and Electrochemistry Research Laboratory, Department of Pure and Applied Chemistry, University of Calaba, P.M.B. 1115 Calabar
  • Magdalene Edet Ikpi Corrosion and Electrochemistry Research Laboratory, Department of Pure and Applied Chemistry, University of Calabar P.M.B. 1115 Calabar
  • Victor E. Okpashi Department of Biochemistry, Cross River University of Technology, Calabar P. M. B.1123
  • Onumashi A. Ushie Department of Chemical Science, Federal University Wukari
  • Mbang E. Obeten Material and Electrochemistry Research group, Department of Chemistry, Cross River University of Technology, Calabar P. M. B 1123
Keywords: Corrosion, density functional theory, potentiodynamic polarization, organic inhibitor, adsorption

Abstract

The inhibitive action of (-)-(S)-9-fluoro-2,3-dihydro-3-methyl-10-(4-methyl-1-piperazinyl)-7-oxo-7H-pyrido[1,2,3-de]-1,4-benzoxazine-6-carboxylic acid (Levaquin) on API 5L X-52 steel in 2 M HCl solution was investigated using potentiodynamic polarization method and quantum chemical study. Levaquin drug showed good inhibition efficiency of 88 and 95 % at 303 and 323 K, respectively. The results of experimental measurements revealed that Levaquin drug works as a mixed type inhibitor. Langmuir thermodynamic model was tested to describe the mode of inhibitor adsorption on the steel surface. The quantum chemical calculations confirmed the efficacy of Levaquin drug as a corrosion inhibitor.

Author Biographies

Fidelis Ebunta Abeng, Material and Electrochemistry Research Group, Department of Chemistry, Cross River University of Technology, Calabar P. M. B 1123 and Corrosion and Electrochemistry Research Laboratory, Department of Pure and Applied Chemistry, University of Calaba, P.M.B. 1115 Calabar
Chemistry Department Lecturer 11
Magdalene Edet Ikpi, Corrosion and Electrochemistry Research Laboratory, Department of Pure and Applied Chemistry, University of Calabar P.M.B. 1115 Calabar

Department of Pure and Applied Chemistry

Associate Professor

References

Y. Qiang, S. Zhang, B. Tan, S. Chen, Corrosion Science 133 (2018) 6-16.

O. A. Abdullatef, Journal of Advances in Chemistry 11 (2015) 3642-3655.

A. A. Siaka, N. O. Eddy, S. O. Idris, L. Magaji, Z. N. Garba, I. S. Shabanda, International Journal of Modern Chemistry 4 (2013) 1-10.

I. Naqvi, A. R. Saleemi, S.Naveed, International Journal of Electrochemical Science 6 (2011) 146-161.

I. A. Akpan, N. O. Offiong, International Journal of Chemistry and Materials Research 2 (2014) 23-29.

I. A. Akpan, N. O. Offiong, Chemical and Process Engineering Research 26 (2014) 20-23.

J. A. Von Fraunhofer, S. H. Stidhan, Journal of Biomedical Engineering 13 (1991) 424- 428.

S. K. Shukla, M. A. Quraishi, Corrosion Science 52 (2010) 314-322.

X. Pang, X. Ran, F. Kuang, J. Xie, B. Hou, Chinese Journal of Chemical Engineering 18 (2010) 337-345.

S. Acharya, S. N. Upadhyay, Transition Indian Institute of Metal 57 (2004) 297-306.

G. Gece, Corrosion Science 53 (2011) 3873-3898.

A. S. Fouda, H. A. Mostafa, H. M. El-Abbasy, Journal of Applied Electrochemistry, 40 (2010) 163-173.

N. O. Eddy, S. A. Odoemelam, Advanced Natural and Applied Science 2 (2008) 225-232.

M. Abdallah, Corrosion Science 46 (2004) 1981-1996.

A. S. Fouda, A. A. Al-Sarawy, F. S. Ahmed, H. M. El-Abbasy, Corrosion Science 51 (2009) 439-702.

X. H. Pang, W. J. Guo, W. H. Li, J. D. Xie, B. R. Hou, Science of China Series B Chemistry 51 (2008) 928 936.

P. O. Ameh, P. Ukoha, P. Ejikeme, N.O. Eddy, Industrial Chemistry 2 (2016) 2469-9764.

S. Kumar, H. Vashisht, L. O.Olasunkanmi, I. Bahadur, H. Verma, G. Singh, I .B. Obot, E. E. Ebenso, Scientific Reports 6 (2016) 30937-30949

J. Bhawsar, P.K. Jain, S. P. Jain, Alexandria Engineering Journal 54 (2015) 769-775.

P. C. Okafor, E. E. Ebenso, U. J. Ekpe, International Journal of Electrochemical Science 5 (2010) 978-993.

A. S. Fouda, G. E. Bekheit, M. W. El-Sherbari, Journal of Bio and Tribo-Corrosion 11 (2016) 1-16.

N. O. Eddy, S. R. Stoyanov, E. E. Ebenso, International Journal of Electrochemical Science 5 (2010) 1127-1150.

M. M. Kabanda, L. C. Murulana, M. Ozcan, F. Karadag, I. Dehri, I. B. Obot, E. E. Ebenso, International Journal of Electrochemical Science 7 (2012) 5035-5056.

H. Elmsellem, H. Nacer, F. Halaimia, A. Aouniti, I. Lakehal, A. Chetouani, S. S. Al-Deyab, I. Warad, R. Touzani, B. Hammouti, International Journal of Electrochemical Science 9 (2014)5329-5351.

G. H. Koch, M. P. H. Brongers, N. G. Thompson, Y. P. Virmani, J. H. Payer, Corrosion cost and preven¬tive strategies, NACE, Houston TX, United States, (2002) 773.

P. O. Ameh, P.U. Koha, N. O. Eddy, Chemical Sciences Journal 6 (2015) doi: 10.4172/2150 3494.1000100

M. Y. Habibat, N. O. Eddy, J. F. Iyum, C. E. Gimba, E. E. Oguzie, Chemical Material Research 2 (2012) 1-12.

R. Chami, M. Boudalia, S. Echihi, M. ElFal,A. Bellaouchou, A. Guenbour, M. Tabyaoui, E. M.Essassi, A. Zarrouk, Y. Ramli, Journal of Materials and Environmental Sciences 8 (2017) 4182-4192.

G. Raja, K. Saravanan, S. Sivakumar, Rasayan Journal of Chemistry 8 (2015) 8-12.

M. E. Mohammed, K. K. Taha, S. A. Khalil, S. A. Talab, International Letters of Chemistry, Physics and Astronomy 14 (2013) 87-102.

M. Lebrini, M. Traisnel, M. Lagrenée, B. Mernari, F. Bentiss, Corrosion Science 50 (2008) 473-479.

B. Tan, S. Zhang, W. Li, X. Zuo, Y. Qiang, L. Xu, J. Hao, S. Chen. Journal of Industrial and Engineering Chemistry 77 (2019) 449-460.

A. A. Khadom, A. N. Abd, N. A. Ahmed, South African Journal of Chemical Engineering 25 (2018) 13-21.

V. C. Anadebe, O. D. Onukwuli, M. Omotioma, N. A. Okafor, South African Journal of Chemistry 71 (2018) 51-61.

T. He, W. Emori, R. H. Zhang, P. C. Okafor, M. Yang C. R. Cheng Bioelectrochemistry, 130 (2019) 107332-107342

M. Ramezanzadeh, G. Bahlakeh, B. Ramezanzadeh, Journal of Molecular Liquids 292 (2019) 111387-111396.

Published
19-05-2020
Section
Electrochemical Science