Experimental and theoretical investigations of new Schiff base compound adsorption on aluminium in 1 M HCl

Original scientific paper

  • Hojat Jafari Department of Chemical Engineering, Shahreza Branch, Islamic Azad University, P.O. Box 311-86145, Shahreza, Iran https://orcid.org/0000-0002-7345-3081
  • Elham Ameri Department of Chemical Engineering, Shahreza Branch, Islamic Azad University, P.O. Box 311-86145 Shahreza, Iran https://orcid.org/0000-0001-7855-2890
  • Fariba Soltanolkottabi Department of Chemical Engineering, Shahreza Branch, Islamic Azad University, P.O. Box 311-86145 Shahreza, Iran
  • Avni Berisha Department of Chemistry, Faculty of Natural and Mathematics Science, University of Prishtina, 10000 Prishtina, Kosovo https://orcid.org/0000-0002-3876-1345
  • Mahamadou Seydou Université de Paris, CNRS, ITODYS UMR 7086, 15 rue J.A. de Baïf, F-75013 Paris, France https://orcid.org/0000-0003-2261-8496
Keywords: Acid corrosion, potentiodynamic polarization, atomic force microscopy, density functional theory
Graphical Abstract

Abstract

The new Schiff base, 2,2'-((1Z,1'Z)-(((propane-1,3-diylbis(oxy))bis(2,1-phenyle­ne))bis­(me­tha­­nyl­­ylidene))bis(azanylylidene))diethanol, was investigated as a cor­ro­sion inhibitor of aluminium in 1 M HCl. Polarization and electrochemical impedance mea­surements were used for this purpose. Polarization curves showed that the compound is a mixed-type corrosion inhibitor. Also, the results showed an increase in inhibition efficiency as the concentration of the compound increased. The maximum corrosion inhibition effici­ency of approximately 81 % was reached at the concentration of 2 mg/L of the inhibitor. The results of the density functional theory method were consistent with the experimental results. The surface morphology of the samples was examined under atomic force microscopy.

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Published
11-08-2022
Section
Electrochemical Science