Environmentally benign synthesis of CuO impregnated activated carbon nanocomposite for prompt bifunctional water splitting applications
Original scientific paper
DOI:
https://doi.org/10.5599/jese.3012Keywords:
Hydrogen evolution reaction, oxygen evolution reaction, electrocatalyst, biomass-derived activated carbon, green hydrogenAbstract
The global pursuit of sustainable energy solutions has intensified the exploration of efficient and eco-friendly methods for hydrogen production, particularly through the hydrogen evolution reaction (HER) from renewable energy sources. Our research focuses on combining bio-waste-derived activated carbon nanomaterials with green-synthesized copper oxide nanoparticles (CuO@AC) to create efficient electrode materials for enhancing HER and oxygen evolution reaction (OER). The surface features of the composite material indicate a nanoarchitectonics of rubble morphology, and multiple intense peaks provide evidence for the successful fabrication of each expected crystalline phase, reflecting the overall composition and structural integrity of the nanomaterials. Findings also make known that CuO nanoparticles combined with activated carbon exhibit high efficiency for both HER and OER activities. It required an overpotential of 137 mV at 10 mA cm-2 current density and a Tafel slope of 94 mV dec-1 to drive the HER, while an overpotential of 194 mV was required to achieve a 10 mA cm-2 current density and a Tafel slope of 67.9 mV dec-1 for the OER catalysis process. This work aims to enhance our understanding of the interactions between activated carbon and metal oxides, highlighting the potential of tailored electrocatalytic materials for sustainable energy conversion and contributing to net-zero emission targets.
Downloads
References
[1] D. Gielen, F. Boshell, D. Saygin, M. D. Bazilian, N. Wagner, R. Gorini, The role of renewable energy in the global energy transformation, Energy Strategy Reviews 24 (2019) 38-50. https://doi.org/10.1016/j.esr.2019.01.006 DOI: https://doi.org/10.1016/j.esr.2019.01.006
[2] R. Hanna, D. G. Victor, Marking the decarbonization revolutions, Nature Energy 6 (2021) 568-571. https://doi.org/10.1038/s41560-021-00854-1 DOI: https://doi.org/10.1038/s41560-021-00854-1
[3] M. Singh, D. R. Paudel, H. Kim, T. H. Kim, J. Park, S. Lee, Interface engineering strategies for enhanced electrocatalytic hydrogen evolution reaction, Energy Advances 4 (2025) 716-742. https://doi.org/10.1039/d5ya00022j DOI: https://doi.org/10.1039/D5YA00022J
[4] S. Gawusu, X. Zhang, A. Ahmed, S. A. Jamatutu, E. D. Miensah, A. A. Amadu, F. A. J. Osei, Renewable energy sources from the perspective of blockchain integration: From theory to application, Sustainable Energy Technologies and Assessments 52 (2022) 102108. https://doi.org/10.1016/j.seta.2022.102108 DOI: https://doi.org/10.1016/j.seta.2022.102108
[5] M. Singh, D. C. Cha, T. I. Singh, A. Maibam, D. R. Paudel, D. H. Nam, T. H. Kim, S. Yoo, S. Lee, A critical review on amorphous-crystalline heterostructured electrocatalysts for efficient water splitting, Materials Chemistry Frontiers 7 (2023) 6254-6280. https://doi.org/10.1039/d3qm00940h DOI: https://doi.org/10.1039/D3QM00940H
[6] D. R. Paudel, U. N. Pan, R. B. Ghising, P. P. Dhakal, V. A. Dinh, H. Wang, N. H. Kim, J. H. Lee, Interface modulation induced by the 1T Co-WS2 shell nanosheet layer at the metallic NiTe2/Ni core-nanoskeleton: Glib electrode-kinetics for HER, OER, and ORR, Nano Energy 102 (2022) 107712. https://doi.org/10.1016/j.nanoen.2022.107712 DOI: https://doi.org/10.1016/j.nanoen.2022.107712
[7] M. A. Khan, H. Zhao, W. Zou, Z. Chen, W. Cao, J. Fang, J. Xu, L. Zhang, J. Zhang, Recent Progresses in Electrocatalysts for Water Electrolysis, Springer Singapore, 2018. https://doi.org/10.1007/s41918-018-0014-z DOI: https://doi.org/10.1007/s41918-018-0014-z
[8] M. Chatenet, B. G. Pollet, D. R. Dekel, F. Dionigi, J. Deseure, P. Millet, R. D. Braatz, M. Z. Bazant, M. Eikerling, I. Staffell, P. Balcombe, Y. Shao-Horn, H. Schäfer, Water electrolysis: from textbook knowledge to the latest scientific strategies and industrial developments, Chemical Society Reviews 51 (2022) 4583-4762. https://doi.org/10.1039/d0cs01079k DOI: https://doi.org/10.1039/D0CS01079K
[9] X. Li, L. Zhao, J. Yu, X. Liu, X. Zhang, H. Liu, W. Zhou, Water Splitting: From Electrode to Green Energy System, Nano-Micro Letters 12 (2020) 131. https://doi.org/10.1007/s40820-020-00469-3 DOI: https://doi.org/10.1007/s40820-020-00469-3
[10] D. R. Paudel, U. N. Pan, T. I. Singh, C. C. Gudal, N. H. Kim, J. H. Lee, Fe and P Doped 1T-Phase Enriched WS2 3D-Dendritic Nanostructures for Efficient Overall Water Splitting, Applied Catalysis B: Environmental 286 (2021) 119897. https://doi.org/10.1016/j.apcatb.2021.119897 DOI: https://doi.org/10.1016/j.apcatb.2021.119897
[11] J. Gautam, Y. Liu, J. Gu, Z. Ma, J. Zha, B. Dahal, L. N. Zhang, A. N. Chishti, L. Ni, G. Diao, Y. Wei, Fabrication of Polyoxometalate Anchored Zinc Cobalt Sulfide Nanowires as a Remarkable Bifunctional Electrocatalyst for Overall Water Splitting, Advanced Functional Materials 31 (2021) 2106147. https://doi.org/10.1002/adfm.202106147 DOI: https://doi.org/10.1002/adfm.202106147
[12] K. Chang, D. T. Tran, J. Wang, S. Prabhakaran, D. H. Kim, N. H. Kim, J. H. Lee, Atomic Heterointerface Engineering of Ni2P-NiSe2 Nanosheets Coupled ZnP-Based Arrays for High-Efficiency Solar-Assisted Water Splitting, Advanced Functional Materials 32 (2022) 2113224. https://doi.org/10.1002/adfm.202113224 DOI: https://doi.org/10.1002/adfm.202113224
[13] P. K. Joshi, S. Dahal, R. K. Rai, G. Bhandari, G. C. Kaphle, D. R. Paudel, Bifunctional Electrocatalysis of Copper-Doped Cerium Oxide Nanocage Networks Enabling HER and OER, Electrocatalysis 16 (2025) 844-855. https://doi.org/10.1007/s12678-025-00961-7 DOI: https://doi.org/10.1007/s12678-025-00961-7
[14] J. Kibsgaard, I. Chorkendorff, Considerations for the scaling-up of water splitting catalysts, Nature Energy 4 (2019) 430-433. https://doi.org/10.1038/s41560-019-0407-1 DOI: https://doi.org/10.1038/s41560-019-0407-1
[15] Z. W. She, J. Kibsgaard, C. F. Dickens, I. Chorkendorff, J. K. Nørskov, T. F. Jaramillo, Combining theory and experiment in electrocatalysis: Insights into materials design, Science 355 (2017). https://doi.org/10.1126/science.aad4998 DOI: https://doi.org/10.1126/science.aad4998
[16] M. Singh, J. Park, H. Kim, G. Kim, D. Cha, D. R. Paudel, B. Kim, S. Lee, Heterointerface‐Driven Electronic Modulation in MoO2@N/Mo‒ReS2 Hybrid for Efficient Alkaline HER, OER, and Overall Water Splitting, Small 21 (2025) 2505906. https://doi.org/10.1002/smll.202505906 DOI: https://doi.org/10.1002/smll.202505906
[17] S. Dahal, P. K . Joshi, N. S. Pandey, S. Gadal, D. R. Paudel, Bifunctional Hydrogen and Oxygen Electrocatalysis of Cerium Doped Copper Oxide Nanostructure, Analytical and Bioanalytical Electrochemistry 17 (2025) 311-326. https://doi.org/10.22034/abec.2025.723273
[18] P. Wang, J. An, Z. Ye, W. Cai, X. Zheng, Cu-Based Multicomponent Metallic Compound Materials as Electrocatalyst for Water Splitting, Frontiers in Chemistry 10 (2022) 913874. https://doi.org/10.3389/fchem.2022.913874 DOI: https://doi.org/10.3389/fchem.2022.913874
[19] J. A. Trindell, Z. Duan, G. Henkelman, R. M. Crooks, Well-Defined Nanoparticle Electrocatalysts for the Refinement of Theory, Chemical Reviews 120 (2020) 814-850. https://doi.org/10.1021/acs.chemrev.9b00246 DOI: https://doi.org/10.1021/acs.chemrev.9b00246
[20] H. M. A. Amin, P. Königshoven, M. Hegemann, H. Baltruschat, Role of Lattice Oxygen in the Oxygen Evolution Reaction on Co3O4: Isotope Exchange Determined Using a Small-Volume Differential Electrochemical Mass Spectrometry Cell Design, Analytical Chemistry 91 (2019) 12653-12660. https://doi.org/10.1021/acs.analchem.9b01749 DOI: https://doi.org/10.1021/acs.analchem.9b01749
[21] H. M. A. Amin, M. Azimzadeh Sani, A. El Arrassi, S. Saddeler, S. Schulz, K. Tschulik, Probing the Intrinsic Oxygen Evolution Kinetics at Single CoFe2O4 Nano‐Catalysts, ChemCatChem 17 (2025) e01234. https://doi.org/10.1002/cctc.202501234 DOI: https://doi.org/10.1002/cctc.202501234
[22] H. M. A. Amin, U. Apfel, Metal‐Rich Chalcogenides as Sustainable Electrocatalysts for Oxygen Evolution and Reduction: State of the Art and Future Perspectives, European Journal of Inorganic Chemistry 2020 (2020) 2679-2690. https://doi.org/10.1002/ejic.202000406 DOI: https://doi.org/10.1002/ejic.202000406
[23] W. Yang, Z. Wang, W. Zhang, S. Guo, Electronic-Structure Tuning of Water-Splitting Nanocatalysts, Trends in Chemistry 1 (2019) 259-271. https://doi.org/10.1016/j.trechm.2019.03.006 DOI: https://doi.org/10.1016/j.trechm.2019.03.006
[24] F. Song, L. Bai, A. Moysiadou, S. Lee, C. Hu, L. Liardet, X. Hu, Transition Metal Oxides as Electrocatalysts for the Oxygen Evolution Reaction in Alkaline Solutions: An Application-Inspired Renaissance, Journal of the American Chemical Society 140 (2018) 7748-7759. https://doi.org/10.1021/jacs.8b04546 DOI: https://doi.org/10.1021/jacs.8b04546
[25] H. A. Younus, Y. Zhang, M. Vandichel, N. Ahmad, K. Laasonen, F. Verpoort, C. Zhang, S. Zhang, Water Oxidation at Neutral pH using a Highly Active Copper-Based Electrocatalyst, ChemSusChem 13 (2020) 5088-5099. https://doi.org/10.1002/cssc.202001444 DOI: https://doi.org/10.1002/cssc.202001444
[26] J. Jeevanandam, S. F. Kiew, S. Boakye-Ansah, S. Y. Lau, A. Barhoum, M. K. Danquah, J. Rodrigues, Green approaches for the synthesis of metal and metal oxide nanoparticles using microbial and plant extracts, Nanoscale 14 (2022) 2534-2571. https://doi.org/10.1039/d1nr08144f DOI: https://doi.org/10.1039/D1NR08144F
[27] H. M. A. Amin, H. Baltruschat, D. Wittmaier, K. A. Friedrich, A Highly Efficient Bifunctional Catalyst for Alkaline Air-Electrodes Based on a Ag and Co3O4 Hybrid: RRDE and Online DEMS Insights, Electrochimica Acta 151 (2015) 332-339. https://doi.org/10.1016/j.electacta.2014.11.017 DOI: https://doi.org/10.1016/j.electacta.2014.11.017
[28] A. S. Sabir, E. Pervaiz, R. Khosa, U. Sohail, An inclusive review and perspective on Cu-based materials for electrochemical water splitting, RSC Advances 13 (2023) 4963-4993. https://doi.org/10.1039/d2ra07901a
[29] Z. Zhou, X. Li, Q. Li, Y. Zhao, H. Pang, Copper-based materials as highly active electrocatalysts for the oxygen evolution reaction, Materials Today Chemistry 11 (2019) 169-196. https://doi.org/10.1016/j.mtchem.2018.10.008 DOI: https://doi.org/10.1016/j.mtchem.2018.10.008
[30] D. R. Paudel, U. N. Pan, R. B. Ghising, M. R. Kandel, S. Prabhakaran, D. H. Kim, N. H. Kim, J. H. Lee, Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen electrocatalysis, Applied Catalysis B: Environmental 331 (2023) 122711. https://doi.org/10.1016/j.apcatb.2023.122711 DOI: https://doi.org/10.1016/j.apcatb.2023.122711
[31] Z. Chen, S. Yun, L. Wu, J. Zhang, X. Shi, W. Wei, Y. Liu, R. Zheng, N. Han, B. J. Ni, Waste-Derived Catalysts for Water Electrolysis: Circular Economy-Driven Sustainable Green Hydrogen Energy, Springer Nature Singapore, 2023. https://doi.org/10.1007/s40820-022-00974-7 DOI: https://doi.org/10.1007/s40820-022-00974-7
[32] Z. Chen, W. Wei, H. Chen, B. J. Ni, Eco-designed electrocatalysts for water splitting: A path toward carbon neutrality, International Journal of Hydrogen Energy 48 (2023) 6288-6307. https://doi.org/10.1016/j.ijhydene.2022.03.046 DOI: https://doi.org/10.1016/j.ijhydene.2022.03.046
[33] A. Muzammil, R. Haider, W. Wei, Y. Wan, M. Ishaq, M. Zahid, W. Yaseen, X. Yuan, Emerging transition metal and carbon nanomaterial hybrids as electrocatalysts for water splitting: a brief review, Materials Horizons 10 (2023) 2764-2799. https://doi.org/10.1039/d3mh00335c DOI: https://doi.org/10.1039/D3MH00335C
[34] N. Prabu, T. Kesavan, G. Maduraiveeran, M. Sasidharan, Bio-derived nanoporous activated carbon sheets as electrocatalyst for enhanced electrochemical water splitting, International Journal of Hydrogen Energy 44 (2019) 19995-20006. https://doi.org/10.1016/j.ijhydene.2019.06.016 DOI: https://doi.org/10.1016/j.ijhydene.2019.06.016
[35] M. Bin Mobarak, M. S. Hossain, F. Chowdhury, S. Ahmed, Synthesis and characterization of CuO nanoparticles utilizing waste fish scale and exploitation of XRD peak profile analysis for approximating the structural parameters, Arabian Journal of Chemistry 15 (2022) 104117. https://doi.org/10.1016/j.arabjc.2022.104117 DOI: https://doi.org/10.1016/j.arabjc.2022.104117
[36] A. Q. Mugheri, A. Tahira, U. Aftab, M. I. Abro, A. L. Bhatti, S. Ali, M. A. Abbasi, Z. H. Ibupoto, A Low Charge Transfer Resistance CuO Composite for Efficient Oxygen Evolution Reaction in Alkaline Media, Journal of Nanoscience and Nanotechnology 21 (2021) 2613-2620. https://doi.org/10.1166/jnn.2021.19091 DOI: https://doi.org/10.1166/jnn.2021.19091
[37] M. Soltani, H. M. A. Amin, A. Cebe, S. Ayata, H. Baltruschat, Metal-Supported Perovskite as an Efficient Bifunctional Electrocatalyst for Oxygen Reduction and Evolution: Substrate Effect, Journal of The Electrochemical Society 168 (2021) 034504. https://doi.org/10.1149/1945-7111/abe8bd DOI: https://doi.org/10.1149/1945-7111/abe8bd
[38] H. M. A. Amin, L. Zan, H. Baltruschat, Boosting the bifunctional catalytic activity of Co3O4 on silver and nickel substrates for the alkaline oxygen evolution and reduction reactions, Surfaces and Interfaces 54 (2024) 105218. https://doi.org/10.1016/j.surfin.2024.105218 DOI: https://doi.org/10.1016/j.surfin.2024.105218
[39] A. Rajput, A. Kundu, B. Chakraborty, Recent Progress on Copper-Based Electrode Materials for Overall Water-Splitting, ChemElectroChem 8 (2021) 1698-1722. https://doi.org/10.1002/celc.202100307 DOI: https://doi.org/10.1002/celc.202100307
[40] D. R. Paudel, G. C. Kaphle, B. R. Poudel, M. KC, M. Singh, G. P. Ojha, Enhanced Hydrogen Evolution Reaction of a Zn+2-Stabilized Tungstate Electrocatalyst, Electrochem 6 (2025) 3. https://doi.org/10.3390/electrochem6010003 DOI: https://doi.org/10.3390/electrochem6010003
[41] W. Zhang, R. Liu, Z. Fan, H. Wen, Y. Chen, R. Lin, Y. Zhu, X. Yang, Z. Chen, Synergistic copper nanoparticles and adjacent single atoms on biomass-derived N-doped carbon toward overall water splitting, Inorganic Chemistry Frontiers 10 (2022) 443-453. https://doi.org/10.1039/d2qi02285k DOI: https://doi.org/10.1039/D2QI02285K
[42] G. Zampardi, J. Thöming, H. Naatz, H. M. A. Amin, S. Pokhrel, L. Mädler, R. G. Compton, Electrochemical Behavior of Single CuO Nanoparticles: Implications for the Assessment of their Environmental Fate, Small 14 (2018) 1801765. https://doi.org/10.1002/smll.201801765 DOI: https://doi.org/10.1002/smll.201801765
[43] Y. Li, Y. Hu, W. You, G. Zhou, G. Peng, A facile method to fabricate AC/CuO for efficient removal of organic pollutants by adsorption and persulfate-based advanced oxidation processes, Journal of Water Supply: Research and Technology - AQUA 70 (2021) 20-29. https://doi.org/10.2166/aqua.2020.094 DOI: https://doi.org/10.2166/aqua.2020.094
[44] D. R. Paudel, R. Kafle, N. Dhital, M. Singh, B. S. Salokhe, Nickel Nanoparticles Infused Iron Tungstate Nanocomposite for Clean Energy Carrier Hydrogen Generation via Water Splitting, Advanced Materials Interfaces 12 (2025) e00644. https://doi.org/10.1002/admi.202500644 DOI: https://doi.org/10.1002/admi.202500644
[45] G. Bhandari, P. P. Dhakal, D. T. Tran, T. H. Nguyen, V. A. Dinh, N. H. Kim, J. H. Lee, Pt Single Atom-Doped Triphasic VP-Ni3P-MoP Heterostructure: Unveiling a Breakthrough Electrocatalyst for Efficient Water Splitting, Small 20 (2024) 2405952. https://doi.org/10.1002/smll.202405952 DOI: https://doi.org/10.1002/smll.202405952
[46] A. Han, H. Zhang, R. Yuan, H. Ji, P. Du, Crystalline Copper Phosphide Nanosheets as an Efficient Janus Catalyst for Overall Water Splitting, ACS Applied Materials & Interfaces 9 (2017) 2240-2248. https://doi.org/10.1021/acsami.6b10983 DOI: https://doi.org/10.1021/acsami.6b10983
[47] S. Wei, K. Qi, Z. Jin, J. Cao, W. Zheng, H. Chen, X. Cui, One-Step Synthesis of a Self-Supported Copper Phosphide Nanobush for Overall Water Splitting, ACS Omega 1 (2016) 1367-1373. https://doi.org/10.1021/acsomega.6b00366 DOI: https://doi.org/10.1021/acsomega.6b00366
[48] J. Hao, W. Yang, Z. Huang, C. Zhang, Superhydrophilic and Superaerophobic Copper Phosphide Microsheets for Efficient Electrocatalytic Hydrogen and Oxygen Evolution, Advanced Materials Interfaces 3 (2016) 1600236. https://doi.org/10.1002/admi.201600236 DOI: https://doi.org/10.1002/admi.201600236
[49] L. Yu, H. Zhou, J. Sun, F. Qin, D. Luo, L. Xie, F. Yu, J. Bao, Y. Li, Y. Yu, S. Chen, Z. Ren, Hierarchical Cu@CoFe layered double hydroxide core-shell nanoarchitectures as bifunctional electrocatalysts for efficient overall water splitting, Nano Energy 41 (2017) 327-336. https://doi.org/10.1016/j.nanoen.2017.09.045 DOI: https://doi.org/10.1016/j.nanoen.2017.09.045
[50] A. S. Sabir, E. Pervaiz, R. Khosa, U. Sohail, An inclusive review and perspective on Cu-based materials for electrochemical water splitting, RSC Advances 13 (2023) 4963-4993. https://doi.org/10.1039/d2ra07901a DOI: https://doi.org/10.1039/D2RA07901A
[51] S. Hong, N. Song, J. Sun, G. Chen, H. Dong, C. Li, Nitrogen-doped biomass carbon fibers with surface encapsulated Co nanoparticles for electrocatalytic overall water-splitting, Chemical Communications 58 (2022) 1772-1775. https://doi.org/10.1039/D1CC06906C DOI: https://doi.org/10.1039/D1CC06906C
[52] X.-X. Ma, L. Chen, Z. Zhang, J.-L. Tang, Electrochemical Performance Evaluation of CuO@Cu2O Nanowires Array on Cu Foam as Bifunctional Electrocatalyst for Efficient Water Splitting, Chinese Journal of Analytical Chemistry 48 (2020) e20001-e20012. https://doi.org/10.1016/S1872-2040(19)61211-9 DOI: https://doi.org/10.1016/S1872-2040(19)61211-9
[53] Z. Guo, X. Wang, Y. Gao, Z. Liu, Co/Cu-modified NiO film grown on nickel foam as a highly active and stable electrocatalyst for overall water splitting, Dalton Transactions 49 (2020) 1776-1784. https://doi.org/10.1039/C9DT04771A DOI: https://doi.org/10.1039/C9DT04771A
[54] Y. Liu, Z. Jin, X. Tian, X. Li, Q. Zhao, D. Xiao, Core-shell copper oxide @ nickel/nickel-iron hydroxides nanoarrays enabled efficient bifunctional electrode for overall water splitting, Electrochimica Acta 318 (2019) 695-702. https://doi.org/10.1016/j.electacta.2019.06.067 DOI: https://doi.org/10.1016/j.electacta.2019.06.067
[55] L. Yin, X. Du, C. Di, M. Wang, K. Su, Z. Li, In-situ transformation obtained defect-rich porous hollow CuO@CoZn-LDH nanoarrays as self-supported electrode for highly efficient overall water splitting, Chemical Engineering Journal 414 (2021) 128809. https://doi.org/10.1016/j.cej.2021.128809 DOI: https://doi.org/10.1016/j.cej.2021.128809
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Tika Bhandari, Rama Kafle, Prakash Ban, Jyoti Ghorsine, Debendra Acharya, Dasu Ram Paudel

This work is licensed under a Creative Commons Attribution 4.0 International License.


