Challenges and control strategies for disrupting passive oxide layer formation in electrochemical machining
Review paper
DOI:
https://doi.org/10.5599/jese.2796Keywords:
Material removal, anodic dissolution, material passivation, process parameters, control measuresAbstract
Electrochemical machining (ECM) is a non-traditional, precision machining process involving the removal of material through anodic dissolution. It is commonly utilized for machining complex geometries in conductive materials, especially in aerospace, biomedical, and automotive sectors. While having numerous benefits, ECM also has a major challenge: the development of a passive oxide layer on the surface of the workpiece. The formation of this layer depends on various factors, such as workpiece material, electrolyte composition, current density, and machining conditions. If not properly controlled, it can cause poor surface finish, dimensional errors, and increased energy consumption. To counter this problem, several control strategies have been devised that play a crucial role in breaking down the passive film. This review critically analyses and compares these strategies for inhibiting passive layer growth in ECM. It highlights both traditional and established techniques as well as novel developments like hybrid ECM methods, AI-driven process optimization, and real-time monitoring systems. The review aims to provide a material-specific and application-oriented perspective, highlighting the advantages, limitations, and technical viability of each strategy. By integrating findings from experimental studies, simulation work, and emerging technologies, this review provides a comprehensive resource for researchers and practitioners seeking to enhance the reliability, performance, and precision of ECM processes in high-tech manufacturing.
Downloads
References
[1] S. A. Silkin, E. A. Pasinkovskii, V. I. Petrenko, A. I. Dikusar, High rate anodic dissolution in chloride solutions of steel after electrothermochemical treatment, Surface Engineering and Applied Electrochemistry 44(5) (2008) 343–352. https://doi: 10.3103/S1068375508050013 DOI: https://doi.org/10.3103/S1068375508050013
[2] L. Jakob, D. Friedemann, E. Nezam, B. Buschke, I. Krossing, J. Bartsch, In-situ evidence for the existence of surface films in electrochemical machining of copper in nitrate electrolytes, Electrochimica Acta 493 (2024) 144391. https://doi.org/10.1016/j.electacta.2024.144391 DOI: https://doi.org/10.1016/j.electacta.2024.144391
[3] D. Zander, A. Schupp, O. Beyss, B. Bob Rommes, A. Klink, Oxide Formation during Transpassive Material Removal of Martensitic 42CrMo4 Steel by Electrochemical Machining, Materials 14(2) (2021) 402. https://doi.org/10.3390/ma14020402 DOI: https://doi.org/10.3390/ma14020402
[4] Y. Liu, N. Qu, Experimental and numerical investigations of reducing stray corrosion and improving surface smooth in macro electrolyte jet machining titanium alloys, Journal of The Electrochemical Society 167(8) (2020) 083502. http://dx.doi.org/10.1149/1945-7111/ab88ba DOI: https://doi.org/10.1149/1945-7111/ab88ba
[5] R.K. Upadhyay, A. Kumar, P.K. Srivastava, Experimental investigations of catalytic effect of Cu2+ during anodic dissolution of iron in NaCl electrolyte. Proceedings of the Institution of Mechanical Engineers B 231(13) (2017) 2408-2415. https://doi.org/10.1177/0954405416629865 DOI: https://doi.org/10.1177/0954405416629865
[6] M. Tak, R. G. Mote, R. G. Anodic dissolution behavior of passive layer during hybrid electrochemical micromachining of Ti6Al4V in NaNO3 solution, Journal of Micro-and Nano-Manufacturing 9(4) (2021) 041001. https://doi.org/10.1115/1.4052327 DOI: https://doi.org/10.1115/1.4052327
[7] T. Haisch, E. Mittemeijer, J. W. Schultze, Electrochemical machining of the steel 100Cr6 in aqueous NaCl and NaNO3 solutions: microstructure of surface films formed by carbides, Electrochimica Acta 47(1-2) (2001) 235-241. https://doi.org/10.1016/S0013-4686(01)00561-8 DOI: https://doi.org/10.1016/S0013-4686(01)00561-8
[8] L. Ying, Z. Yongbin, Z. Rudong, L. Yanliang, Electrochemical dissolution behavior and characterisation of passivation films of PH13-8Mo in NaNO3, Journal of Electroanalytical Chemistry 981 (2025) 119004. https://doi.org/10.1016/j.jelechem.2025.119004 DOI: https://doi.org/10.1016/j.jelechem.2025.119004
[9] M.M. Lohrengel, K.P. Rataj, T. Münninghoff, Electrochemical machining—mechanisms of anodic dissolution, Electrochimica Acta 201 (2016) 348-353. http://dx.doi.org/10.1016/j.electacta.2015.12.219 DOI: https://doi.org/10.1016/j.electacta.2015.12.219
[10] P.B. Tailor, A. Agrawal, S.S. Joshi, Numerical modeling of passive layer formation and stabilization in electrochemical polishing process, Journal of Manufacturing Processes 18 (2015) 107-116. https://doi.org/10.1016/j.jmapro.2015.02.001 DOI: https://doi.org/10.1016/j.jmapro.2015.02.001
[11] J. Mitchell-Smith, A.T. Clare, Electrochemical jet machining of titanium: overcoming passivation layers with ultrasonic assistance, Procedia CIRP 42 (2016) 379-383. https://doi.org/10.1016/j.procir.2016.02.215 DOI: https://doi.org/10.1016/j.procir.2016.02.215
[12] F. Klocke, S. Harst, L. Ehle, M. Zeis, A. Klink, Surface integrity in electrochemical machining processes: An analysis on material modifications occurring during electrochemical machining, Proceedings of the Institution of Mechanical Engineers B 232(4) (2018) 578-585. https://doi.org/10.1177/0954405417703422 DOI: https://doi.org/10.1177/0954405417703422
[13] J. Liu, X. Adayi, Effect of mechanical action and passive film on electrochemical mechanical finishing, The International Journal of Advanced Manufacturing Technology 112 (2021) 1787-1795. https://doi.org/10.1007/s00170-020-06510-4 DOI: https://doi.org/10.1007/s00170-020-06510-4
[14] J. Wang, Y. Wang, X. Shi, P. Ouyang, Z. Zhang, H. Zhu, H, Y. Liu, Anodic dissolution behavior and microstructure preparation of nickel based superalloy in cryogenic-shielded and laser-assisted electrochemical machining, Journal of Materials Processing Technology 338 (2025) 118777. http://dx.doi.org/10.1016/j.jmatprotec.2025.118777 DOI: https://doi.org/10.1016/j.jmatprotec.2025.118777
[15] H. Yurtkuran, An evaluation on machinability characteristics of titanium and nickel based superalloys used in aerospace industry, İmalat Teknolojileri ve Uygulamaları 2(2) (2021) 10-29. http://dx.doi.org/10.52795/mateca.940261 DOI: https://doi.org/10.52795/mateca.940261
[16] J. Wang, S. Yang, J. Zhang, Z. Zhang, W. Xue, H. Zhu, Y. Liu, Corrosion Properties and Passive Film Interface of Inconel 718 in NaNO3 Solution for Laser-Assisted Electrochemical Machining, Langmuir 40(28) (2024) 14384-14398. https://doi.org/10.1021/acs.langmuir.4c00993 DOI: https://doi.org/10.1021/acs.langmuir.4c00993
[17] Y. Yin, J. Zhang, Y. Ma, J. Huo, K. Zhao, X. Meng, J. Yin, Electrochemical dissolution behavior of nickel-based Hastelloy X superalloy at low current densities, IEEE Access 8 (2020) 62714-62724. http://dx.doi.org/10.1109/ACCESS.2020.2983591 DOI: https://doi.org/10.1109/ACCESS.2020.2983591
[18] H. Chen, L. Shi, Z.Y. Wang, S.Q. Yu, Electrochemical micro machining of stainless steel in EDTA complex electrolyte, Applied Mechanics and Materials 446 (2014) 214-218. https://doi.org/10.4028/www.scientific.net/AMM.446-447.214 DOI: https://doi.org/10.4028/www.scientific.net/AMM.446-447.214
[19] Z. Zhang, R. S. B. Dandu, E. E. Klu, W. Cai, A review on tribocorrosion behavior of aluminum alloys: From fundamental mechanisms to alloy design strategies, Corrosion and Materials Degradation 4(4) (2023) 594-622. https://doi.org/10.3390/cmd4040031 DOI: https://doi.org/10.3390/cmd4040031
[20] Y. Wang, P. Z. Zhang, H.Y. Wu, X.F. Wei, Q. Bi, J. Song, Microstructure and electrochemical properties of plasma tantalumising on low carbon steel, Surface Engineering 31(8) (2015) 634-640. https://doi.org/10.1179/1743294414Y.0000000374 DOI: https://doi.org/10.1179/1743294414Y.0000000374
[21] S. Zhang, J. Liu, X. Lin, Y. Huang, M. Wang, Y. Zhang, W. Huang, Effect of electrolyte solutions on the electrochemical dissolution behavior of additively manufactured Hastelloy X superalloy via laser solid forming, Journal of Alloys and Compounds 878 (2021) 160395. https://doi.org/10.1016/j.jallcom.2021.160395 DOI: https://doi.org/10.1016/j.jallcom.2021.160395
[22] A. Thakur, M. Tak, R. G. Mote, Electrochemical micromachining behavior on 17-4 PH stainless steel using different electrolytes, Procedia Manufacturing 34 (2019) 355-361. http://dx.doi.org/10.1016/j.promfg.2019.06.177 DOI: https://doi.org/10.1016/j.promfg.2019.06.177
[23] S. S. Anasane, B. Bhattacharyya, Experimental investigation on suitability of electrolytes for electrochemical micromachining of titanium, The International Journal of Advanced Manufacturing Technology 86 (2016) 2147-2160. https://doi.org/10.1007/s00170-015-8309-2 DOI: https://doi.org/10.1007/s00170-015-8309-2
[24] M. Datta, D. Landolt, On the influence of electrolyte concentration, pH and temperature on surface brightening of nickel under ECM conditions, Journal of Applied Electrochemistry 7 (1977) 247-252. https://doi.org/10.1007/BF00618992 DOI: https://doi.org/10.1007/BF00618992
[25] S. S. Shinde, N. K. Wagh, S. H. Kim, J. H. Lee, Li, Na, K, Mg, Zn, Al, and Ca Anode Interface Chemistries Developed by Solid‐State Electrolytes, Advanced Science 10(32) (2023) 2304235. https://doi.org/10.1002/advs.202304235 DOI: https://doi.org/10.1002/advs.202304235
[26] X. Fang, N. Qu, Y. Zhang, Z. Xu, D. Zhu, Effects of pulsating electrolyte flow in electrochemical machining, Journal of Materials Processing Technology 214(1) (2014) 36-43. http://dx.doi.org/10.1016/j.jmatprotec.2013.07.012 DOI: https://doi.org/10.1016/j.jmatprotec.2013.07.012
[27] M. Datta, D. Landolt, On the role of mass transport in high rate dissolution of iron and nickel in ECM electrolytes—II, Chlorate and nitrate solutions, Electrochimica Acta 25(10) (1980) 1263-1271. https://doi.org/10.1016/0013-4686 DOI: https://doi.org/10.1016/0013-4686(80)87131-3
[28] M. A. Rabbo, P. J. Boden, Development of Electrolytes for the Electrochemical Machining of Titanium I. Electrochemistry in static solutions, British Corrosion Journal 14(4) (1979) 240-245. https://doi.org/10.1179/000705979798358526 DOI: https://doi.org/10.1179/000705979798358526
[29] C. Rosenkranz, M. M Lohrengel, J. W. Schultze, The surface structure during pulsed ECM of iron in NaNO3, Electrochimica Acta 50(10) (2005) 2009-2016. https://doi.org/10.1016/j.electacta.2004.09.010 DOI: https://doi.org/10.1016/j.electacta.2004.09.010
[30] E. V Likrizon, S. A. Silkin, A. I. Dikusar, Effect of Passive Oxide Film Structure and Surface Temperature on the Rate of Anodic Dissolution of Chromium-Nickel and Titanium Alloys in Electrolytes for Electrochemical Machining: Part 2. Anodic Dissolution of Titanium Alloys in Nitrate and Chloride Solutions, Surface Engineering and Applied Electrochemistry 59(3) (2023) 255-263. http://dx.doi.org/10.52577/eom.2022.58.3.01 DOI: https://doi.org/10.3103/S1068375523030134
[31] X. Chen, Z. Xu, D. Zhu, Z. Fang, D. Zhu, Experimental research on electrochemical machining of titanium alloy Ti60 for a blisk, Chinese Journal of Aeronautics 29(1) (2016) 274-282. http://dx.doi.org/10.1016/j.cja.2015.09.010 DOI: https://doi.org/10.1016/j.cja.2015.09.010
[32] R. K Pandey, P. Senthil, L. Boriwal, A. Malviya, Experimental investigation on influence of ECM process parameters on responses using full factorial design, Materials Today: Proceedings 4(2) (2017) 3666-3671. https://doi.org/10.1016/j.matpr.2017.02.260 DOI: https://doi.org/10.1016/j.matpr.2017.02.260
[33] B. Bhattacharyya, J. Munda, Experimental investigation on the influence of electrochemical machining parameters on machining rate and accuracy in micromachining domain, International Journal of Machine Tools and Manufacture 43(13) (2003) 1301-1310. https://doi.org/10.1016/S0890-6955(03)00161-5 DOI: https://doi.org/10.1016/S0890-6955(03)00161-5
[34] O. Weber, M. Weinmann, H. Natter, D. Bähre, Electrochemical dissolution of cast iron in NaNO3 electrolyte, Journal of Applied Electrochemistry 45 (2015) 591-609. http://dx.doi.org/10.1007/s10800-015-0809-0 DOI: https://doi.org/10.1007/s10800-015-0809-0
[35] R.V Rao, P.J. Pawar, R. Shankar, Multi-objective optimization of electrochemical machining process parameters using a particle swarm optimization algorithm, Proceedings of the Institution of Mechanical Engineers Part B: Journal of Engineering Manufacture 222(8) (2008) 949-958. https://doi.org/10.1243/09544054JEM1158 DOI: https://doi.org/10.1243/09544054JEM1158
[36] A. K. Swain, M. M. Sundaram, K. P. Rajurkar, Use of coated microtools in advanced manu-fac¬turing: An exploratory study in electrochemical machining (ECM) context, Journal of Manu¬facturing Processes 14(2) (2012) 150-159. https://doi.org/10.1016/j.jmapro.2011.11.005 DOI: https://doi.org/10.1016/j.jmapro.2011.11.005
[37] M. M. Lohrengel, I. Klüppel, C. Rosenkranz, H. Bettermann, J. W. Schultze, Microscopic investigations of electrochemical machining of Fe in NaNO3. Electrochimica Acta 48(20-22) (2003) 3203-3211. http://dx.doi.org/10.1016/S0013-4686(03)00372-4 DOI: https://doi.org/10.1016/S0013-4686(03)00372-4
[38] V. M. Volgin, V. V. Lyubimov, T. B. Kabanova, A. D. Davydov, Theoretical analysis of micro/nano electrochemical machining with ultra-short voltage pulses, Electrochimica Acta 369 (2021) 137666. https://doi.org/10.1016/j.electacta.2020.137666 DOI: https://doi.org/10.1016/j.electacta.2020.137666
[39] X. Ma, X. Hu, S. Fan, H. Li, Electrochemical dissolution behavior of passive films of titanium matrix composites in NaCl solution, The International Journal of Advanced Manufacturing Technology 129(9) (2023) 3813-3828. https://doi.org/10.1007/s00170-023-12463-1 DOI: https://doi.org/10.1007/s00170-023-12463-1
[40] Y. Yin, H. Li, S. Pan, J. Zhang, Q. Han, S. Yang, Electrochemical behaviour of passivation film formed on SLM-fabricated Hastelloy X superalloy surface in 10 wt% NaNO3 solution, Corrosion Science 206 (2022) 110494. https://doi.org/10.1016/j.corsci.2022.110494 DOI: https://doi.org/10.1016/j.corsci.2022.110494
[41] Y. He, J. Zhao, H. Xiao, W. Lu, W. Gan, F. Yin, Z. Yang, Electrochemical machining of titanium alloy based on NaCl electrolyte solution, International Journal of Electrochemical Science 13(6) (2018) 5736-5747. https://doi.org/10.20964/2018.06.31 DOI: https://doi.org/10.20964/2018.06.31
[42] G. Liu, Z. Gong, Y. Yang, J. Shi, Y. Liu, X. Dou, C. Li, Electrochemical dissolution behavior of stainless steels with different metallographic phases and its effects on micro electrochemical machining performance, Electrochemistry Communications 160 (2024) 107677. https://doi.org/10.1016/j.elecom.2024.107677 DOI: https://doi.org/10.1016/j.elecom.2024.107677
[43] Y. Wang, Z. Xu, A. Zhang, Electrochemical dissolution behavior of Ti-45Al-2Mn-2Nb+ 0.8 vol% TiB2 XD alloy in NaCl and NaNO3 solutions, Corrosion Science 157 (2019) 357-369. https://doi.org/10.1016/j.corsci.2019.06.010 DOI: https://doi.org/10.1016/j.corsci.2019.06.010
[44] G. Singh, H. Kumar, A. Kumar, Variations in Surface Roughness and Material Removal by using Chemical/Chemically Assisted/Hybrid Machining Processes - A Review, Indian Journal of Science and Technology 11 (2018) 28. https://dx.doi.org/10.17485/ijst/2018/v11i28/130785 DOI: https://doi.org/10.17485/ijst/2018/v11i28/130785
[45] E. Nam, C. Y. Lee, J. Min, S. J. Lee, B. K. Min, Effect of electrochemical conditions on material removal rate in electrochemical oxidation assisted machining. Journal of The Electrochemical Society, 164(2) (2017) E23. https://doi.org/10.1149/2.0061704jes DOI: https://doi.org/10.1149/2.0061704jes
[46] P. Rodriguez, D. Hidalgo, J. E. Labarga, Optimization of pulsed electrochemical micromachining in stainless steel, Procedia CIRP 68 (2018) 426-431. https://doi.org/10.1016/j.procir.2017.12.090 DOI: https://doi.org/10.1016/j.procir.2017.12.090
[47] W. Cao, D. Wang, D. Zhu, D. Improvement of surface quality for titanium alloys during counter-rotating electrochemical machining using an auxiliary cathode, Journal of The Electrochemical Society 169(12) (2022) 123506. http://dx.doi.org/10.1149/1945-7111/acad2f DOI: https://doi.org/10.1149/1945-7111/acad2f
[48] A. I. Dikusar, E. V. Likrizon, Effect of the Structure of Passive Oxide Films and Surface Temperature on the Rate of Anodic Dissolution of Chromium–Nickel and Titanium Alloys in Electrolytes for Electrochemical Machining: Part 1. Anodic Dissolution of Chromium–Nickel Steel in a Nitrate Solution, Surface Engineering and Applied Electrochemistry 59(2) (2023) 107-115. http://dx.doi.org/10.3103/S1068375523020047 DOI: https://doi.org/10.3103/S1068375523020047
[49] Y. Wang, N. Qu, Effect of breakdown behavior of passive films on the electrochemical jet milling of titanium alloy TC4 in sodium nitrate solution, International Journal of Electrochemical Science 14(2) (2019) 1116-1131. https://doi.org/10.20964/2019.02.05 DOI: https://doi.org/10.20964/2019.02.05
[50] Z. Feng, E. Granda, W. Hung, Experimental investigation of vibration-assisted pulsed electrochemical machining, Procedia Manufacturing 5 (2016) 798-814. http://dx.doi.org/10.1016/j.promfg.2016.08.065 DOI: https://doi.org/10.1016/j.promfg.2016.08.065
[51] V. K. Jain, A. K. Chouksey, A comprehensive analysis of three-phase electrolyte conductivity during electrochemical macromachining/micromachining, Proceedings of the Institution of Mechanical Engineers B 232(14) (2018) 2449-2461. https://doi.org/10.1177/0954405417690558 DOI: https://doi.org/10.1177/0954405417690558
[52] M. Datta, Anodic dissolution of metals at high rates, IBM Journal of Research and Development 37(2) (1993) 207-226. https://doi.org/10.1147/rd.372.0207 DOI: https://doi.org/10.1147/rd.372.0207
[53] J. P. Hoare, M. A. LaBoda, M. L. McMillan, A. J. Wallace, An Investigation of the differences between NaCl and NaClO3 as electrolytes in electrochemical machining, Journal of The Electrochemical Society 116(2) (1969) 199. http://dx.doi.org/10.1149/1.2411795 DOI: https://doi.org/10.1149/1.2411795
[54] F. Shen, Y, Zhu, X, Li, R, Luo, Q. Tu, J. Wang, N. Huang, Vascular cell responses to ECM produced by smooth muscle cells on TiO2 nanotubes, Applied Surface Science 349 (2015) 589-598. https://doi.org/10.1016/j.apsusc.2015.05.042 DOI: https://doi.org/10.1016/j.apsusc.2015.05.042
[55] L. An, D. Wang, D. Zhu, Improvement on surface quality of 316L stainless steel fabricated by laser powder bed fusion via electrochemical polishing in NaNO3 solution, Journal of Manufacturing Processes 83 (2022) 325-338. https://doi.org/10.1016/j.jmapro.2022.09.005 DOI: https://doi.org/10.1016/j.jmapro.2022.09.005
[56] Y. Dai, Q. Li, H. Gao, L.Q. Li, F.N. Chen, F. Luo, S.Y. Zhang, Effects of five additives on electrochemical corrosion behaviours of AZ91D magnesium alloy in sodium chloride solution, Surface Engineering 27(7) (2011) 536-543. https://doi.org/10.1051/e3sconf/202339101168 DOI: https://doi.org/10.1179/1743294410Y.0000000025
[57] R. Mishra, R. P. Singh, R. K. Garg, Investigation into micro slotting of Cu-based shape memory alloy via µ-ECM using ethylene glycol mixed aqueous NaCl electrolyte, Canadian Metal¬lurgical Quarterly 64(3) (2024) 1063-1077. https://doi.org/10.1080/00084433.2024.2419224 DOI: https://doi.org/10.1080/00084433.2024.2419224
[58] D. Gelman, I. Lasman, S. Elfimchev, D. Starosvetsky, Y. Ein-Eli, Aluminum corrosion mitigation in alkaline electrolytes containing hybrid inorganic/organic inhibitor system for power sources applications, Journal of Power Sources 285 (2015) 100-108. https://doi.org/10.1016/j.jpowsour.2015.03.048 DOI: https://doi.org/10.1016/j.jpowsour.2015.03.048
[59] N. Vangapally, S. A. Gaffoor, S. K. Martha, Na2EDTA chelating agent as an electrolyte additive for high performance lead-acid batteries, Electrochimica Acta 258 (2017) 1493-1501. https://doi.org/10.1016/j.electacta.2017.12.028 DOI: https://doi.org/10.1016/j.electacta.2017.12.028
[60] G. Yang, B. Wang, K. Tawfiq, H. Wei, S. Zhou, G. Chen, Electropolishing of surfaces: theory and applications, Surface Engineering 33(2) (2017) 149-166. http://dx.doi.org/10.1080/02670844.2016.1198452 DOI: https://doi.org/10.1080/02670844.2016.1198452
[61] G. Cercal, G. de Alvarenga, M. Vidotti, Sludge Reduction and Surface Investigation in Electrochemical Machining by Complexing and Reducing Agents, Processes 11(7) (2023) 2186. https://doi.org/10.3390/pr11072186 DOI: https://doi.org/10.3390/pr11072186
[62] N. N. Zurita-Mendez, G. Carbajal-De la Torre, M. Estevez, L. Ballesteros-Almanza, E. Cadenas, M.A. Espinosa-Medina, Evaluation of the electrochemical behavior of TiO2/Al2O3/PCL composite coatings in Hank's solution, Materials Chemistry and Physics 235 (2019) 121773. https://doi.org/10.1016/j.matchemphys.2019.121773 DOI: https://doi.org/10.1016/j.matchemphys.2019.121773
[63] L. Freire, M. J. Carmezim, M. A. Ferreira, M. F. Montemor, The passive behaviour of AISI 316 in alkaline media and the effect of pH: A combined electrochemical and analytical study, Electro¬chimica Acta 55(21) (2010) 6174-6181. https://doi.org/10.1016/j.electacta.2009.10.026 DOI: https://doi.org/10.1016/j.electacta.2009.10.026
[64] M. C. Weidman, D. V. Esposito, I. J. Hsu, J. . Chen, Electrochemical stability of tungsten and tungsten monocarbide (WC) over wide pH and potential ranges, Journal of The Electrochemical Society 157(12) (2010) F179. https://doi.org/10.1149/1.3491341 DOI: https://doi.org/10.1149/1.3491341
[65] A. Dalmau, V.G. Pina, F. Devesa, V. Amigó, A.I. Muñoz, Electrochemical behavior of near-beta titanium biomedical alloys in phosphate buffer saline solution, Materials Science and Engineering: C 48 (2015) 55-62. https://doi.org/10.1016/j.msec.2014.11.036 DOI: https://doi.org/10.1016/j.msec.2014.11.036
[66] M. Anik, K. Osseo-Asare, Effect of pH on the anodic behavior of tungsten, Journal of The Electrochemical Society 149(6) (2002) B224. https://doi.org/10.1149/1.1471544 DOI: https://doi.org/10.1149/1.1471544
[67] S.H. Sarraf, S. Rastegari, M. Soltanieh, M. Deposition of mono dispersed Co–CeO2 nanocomposite coatings by a sol-enhanced pulsed reverse electroplating: process parameters screening, Journal of Materials Research and Technology 23 (2023) 3772-3789. https://doi.org/10.1016/j.jmrt.2023.02.036 DOI: https://doi.org/10.1016/j.jmrt.2023.02.036
[68] O. D. Oniku, R. Regojo, Z. Kaufman, W. C. Patterson, D. P. Arnold, Batch patterning of submillimeter features in hard magnetic films using pulsed magnetic fields and soft magnetizing heads, IEEE Transactions on Magnetics 49(7) (2013) 4116-4119. https://doi.org/10.1109/TMAG.2013.2237891 DOI: https://doi.org/10.1109/TMAG.2013.2237891
[69] C. Gao, N. Qu, H. He, L. Meng, L. Double-pulsed wire electrochemical micro-machining of type-304 stainless steel, Journal of Materials Processing Technology, 266 (2019) 381-387. https://doi.org/10.1016/j.jmatprotec.2018.11.018 DOI: https://doi.org/10.1016/j.jmatprotec.2018.11.018
[70] A. I. Dikusar, S. A. Silkin, Formation and breakdown of oxide films in high-rate anodic dissolution of chromium–nickel steels in electrolytes for electrochemical machining, Surface Engineering and Applied Electrochemistry 58(4) (2022) 313-322. http://dx.doi.org/10.3103/S1068375522040056 DOI: https://doi.org/10.3103/S1068375522040056
[71] J. Wang, Z. Xu, T. Geng, D. Zhu, Dependency of the pulsed electrochemical machining characteristics of Inconel 718 in NaNO3 solution on the pulse current, Science China Technological Sciences 65(10) (2022) 2485-2502. https://doi.org/10.1007/s11431-021-2043-9 DOI: https://doi.org/10.1007/s11431-021-2043-9
[72] M. R. Akbarpour, F. Gharibi Asl, H. Rashedi, F. S. Torknik, Evaluation of Corrosion Resistance of Ni-Co/Gr Nanocomposite Coating Applied on Carbon Steel Substrate by Electro-Deposition Method under Pulse-Reverse Current, Journal of Advanced Materials and Technologies 11(3) (2022) 43-55. https://doi.org/10.30501/jamt.2022.299055.1190
[73] V. Rajput, M. Goud, N. M. Suri, Electrochemical discharge machining: gas film electrochemical aspects, stability parameters, and research work, Journal of The Electrochemical Society 168(1) (2021) 013503. https://doi.org/10.1149/1945-7111/abd516 DOI: https://doi.org/10.1149/1945-7111/abd516
[74] N. Smets, S. Van Damme, D. De Wilde, G. Weyns, J. Deconinck, Time-averaged concen¬tra-tion calculations in pulse electrochemical machining, spectral approach, Journal of Applied Electrochemistry, 39 (2009) 2481-2488. http://dx.doi.org/10.1007/s10800-008-9608-1 DOI: https://doi.org/10.1007/s10800-009-9945-8
[75] F. Wang, J. Yao, M. Kang, Electrochemical machining of a rhombus hole with synchronization of pulse current and low-frequency oscillations, Journal of Manufacturing Processes 57 (2020) 91-104. https://doi.org/10.1016/j.jmapro.2020.06.014 DOI: https://doi.org/10.1016/j.jmapro.2020.06.014
[76] A. Kumar, B. S. Pabla, Review on optimized process parameters of electrochemical machining and its variants, Materials Today: Proceedings, 46 (2021) 10854-10860. https://doi.org/10.1016/j.matpr.2021.01.807 DOI: https://doi.org/10.1016/j.matpr.2021.01.807
[77] M. Painuly, R.P. Singh, R. Trehan, Investigation into electrochemical machining of aviation grade inconel 625 super alloy: an experimental study with advanced optimization and microstructural analysis, Aircraft Engineering and Aerospace Technology 97(2) (2025) 137-148. https://doi.org/10.1108/AEAT-08-2023-0211 DOI: https://doi.org/10.1108/AEAT-08-2023-0211
[78] G. Cui, D. Wang, Z. Zhu, W. Cao, T. Fu, Improvement on leveling ability in counter-rotating elec¬trochemical machining by using a variable voltage, The International Journal of Advanced Ma¬nufacturing Technology 132(1) (2024) 553-569. http://dx.doi.org/10.1007/s00170-024-13395-0 DOI: https://doi.org/10.1007/s00170-024-13395-0
[79] Z. Zhou, X. Fang, Y. Zeng, D. Zhu, Research on machining gap distribution in wire electrochemical micromachining, Journal of The Electrochemical Society 168(4) (2021) 043503. http://dx.doi.org/10.1149/1945-7111/abf79c DOI: https://doi.org/10.1149/1945-7111/abf79c
[80] G. Liu, Y. Zhang, W. Natsu, Influence of electrolyte flow mode on characteristics of electrochemical machining with electrolyte suction tool, International Journal of Machine Tools and Manufacture 142 (2019) 66-75. https://doi.org/10.1016/j.ijmachtools.2019.04.010 DOI: https://doi.org/10.1016/j.ijmachtools.2019.04.010
[81] M. Painuly, R.P. Singh, R. Trehan, Investigation into surface quality of Inconel 625 processed with micro-electrochemical machining, Journal of Solid State Electrochemistry 29(4) (2025) 1543-1559. https://doi.org/10.1007/s10008-024-06156-2 DOI: https://doi.org/10.1007/s10008-024-06156-2
[82] J. Wang, Z. Xu, J. Wang, D. Zhu, Electrochemical machining on blisk channels with a variable feed rate mode, Chinese Journal of Aeronautics 34(6) (2021) 151-161. https://doi.org/10.1016/j.cja.2020.08.002 DOI: https://doi.org/10.1016/j.cja.2020.08.002
[83] M. Painuly, R. P. Singh, R. Trehan, Simulation and experimental study for enhancing surface integrity of micro-slots processed on Nimonic-263 super alloy via electrochemical machining, Materials and Manufacturing Processes 39(13) (2024) 1842-1856. https://doi.org/10.1080/10426914.2024.2368551 DOI: https://doi.org/10.1080/10426914.2024.2368551
[84] R. N. Yadav, Electro-chemical spark machining–based hybrid machining processes: research trends and opportunities, Proceedings of the Institution of Mechanical Engineers B 233(4) (2019) 1037-1061. https://doi.org/10.1177/0954405418755825 DOI: https://doi.org/10.1177/0954405418755825
[85] S. Li, Y. Wu, M. Nomura, T. Fujii, Fundamental machining characteristics of ultrasonic-assisted electrochemical grinding of Ti–6Al–4V, Journal of Manufacturing Science and Engineering 140(7) (2018) 071009. https://doi.org/10.1115/1.4039855 DOI: https://doi.org/10.1115/1.4039855
[86] Y. Xue, Z. Wang, Effect of Micro abrasion on Corrosion Behavior of NiTi Alloy in PBS Solution, Journal of Bio-and Tribo-Corrosion 6(3) (2020) 72. http://dx.doi.org/10.1007/s40735-020-00365-8 DOI: https://doi.org/10.1007/s40735-020-00365-8
[87] W. Choi, H. C. Shin, J. M. Kim, J. Y. Choi, W. S. Yoon, Modeling and applications of electrochemical impedance spectroscopy (EIS) for lithium-ion batteries, Journal of Electrochemical Science and Technology 11(1) (2020) 1-13. http://dx.doi.org/10.33961/jecst.2019.00528 DOI: https://doi.org/10.33961/jecst.2019.00528
[88] H. Taheri, M. G. Bocanegra, M. Taheri, Artificial Intelligence, Machine Learning and Smart Technologies for Nondestructive Evaluation, Sensors 22(11) (2022) 4055. https://doi.org/10.3390/s22114055 DOI: https://doi.org/10.3390/s22114055
[89] R. Uddin, I. Koo, Real-time remote patient monitoring: a review of biosensors integrated with multi-hop IoT systems via cloud connectivity, Applied Sciences 14(5) (2024) 1876. https://doi.org/10.3390/app14051876 DOI: https://doi.org/10.3390/app14051876
[90] V. J. Pulikkottil, S. Chidambaram, P. U. Bejoy, P. K. Femin, P. Paul, M. Rishad, Corrosion resistance of stainless steel, nickel-titanium, titanium molybdenum alloy, and ion-implanted titanium molybdenum alloy archwires in acidic fluoride-containing artificial saliva: An: in vitro: study, Journal of Pharmacy and Bioallied Sciences 8(1) (2016) S96-S99. https://doi.org/10.4103/0975-7406.192032 DOI: https://doi.org/10.4103/0975-7406.192032
[91] C. Guo, J. Qian, D. Reynaerts, A three-dimensional FEM model of channel machining by scanning micro electrochemical flow cell and jet electrochemical machining, Precision Engineering 52 (2018) 507-519. https://doi.org/10.1016/j.precisioneng.2018.02.002 DOI: https://doi.org/10.1016/j.precisioneng.2018.02.002
[92] B. R Acharya, S. Nayak, A. Mallick, CFD Analysis of Electrolyte Flow in Electrochemical Machining, JP Journal of Heat and Mass Transfer 17 (2019) 203-214. http://dx.doi.org/10.17654/HM017010203 DOI: https://doi.org/10.17654/HM017010203
[93] V. Rajput, M. Goud, N. M. Suri, Finite element modeling for comparing the machining performance of different electrolytes in ECDM, Arabian Journal for Science and Engineering 46 (2021) 2097-2119. http://dx.doi.org/10.1007/s13369-020-05009-0 DOI: https://doi.org/10.1007/s13369-020-05009-0
[94] D. B. Jadhav, P. V. Jadhav, D. S. Bilgi, A. A. Sawant, Experimental investigation of MRR on inconel 600 using ultrasonic assisted pulse electrochemical machining, IOP Conference Series: Materials Science and Engineering 377(1) (2018) 012095. http://dx.doi.org/10.1088/1757-899X/377/1/012095 DOI: https://doi.org/10.1088/1757-899X/377/1/012095
[95] M. N. Ali, S. Chakravarty, P. Haldar, Experimental Investi gation and Optimization of MRR in μ-ECDM Process by Taguchi, RSM, PSO and ANN, Suranaree Journal of Science and Technology 29(5) (2022). https://doi.org/10.3390/ma14195820 DOI: https://doi.org/10.3390/ma14195820
[96] Y. Zhang, F. Gu, C. Chen, F.B. Mhahe, S. He, Research on machining Technology of Electrospark-electrochemical Hybrid Energy Field with tungsten hole, International Journal of Refractory Metals and Hard Materials 123 (2024) 106759. http://dx.doi.org/10.1016/j.ijrmhm.2024.106759 DOI: https://doi.org/10.1016/j.ijrmhm.2024.106759
[97] B. Mouliprasanth, P. Hariharan, Influence of variant electrolyte in electrochemical micromachining of micro holes in SMA using Taguchi optimization, Russian Journal of Electrochemistry 57(3) (2021) 197-213. http://dx.doi.org/10.1134/S1023193521030095 DOI: https://doi.org/10.1134/S1023193521030095
[98] E. J. Taylor, Developing industrial applications of pulse electrolytic processes, Electrochemical Society Meeting Abstracts MA2023-02 (2023) 1393-1393. The Electrochemical Society, Inc. http://dx.doi.org/10.1149/MA2023-02261393mtgabs DOI: https://doi.org/10.1149/MA2023-02261393mtgabs
[99] S. Saha, A.K. Mondal, R. Čep, H. Joardar, B. Haldar, A. Kumar, S. Ataya, Multi-response optimization of electrochemical machining parameters for Inconel 718 via RSM and MOGA-ANN, Machines 12(5) (2024) 335. https://doi.org/10.3390/machines12050335 DOI: https://doi.org/10.3390/machines12050335
[100] A. Pawar, D. Kamble, D.B. Jadhav, Experimental investigation on titanium alloys for machin¬ing of stepped circular holes using ultrasonic-assisted hybrid ECM, Journal of Engineering and Applied Science 71(1) (2024) 58. https://doi.org/10.1186/s44147-024-00395-w DOI: https://doi.org/10.1186/s44147-024-00395-w
[101] C. Micallef, Y. Zhuk, A.I. Aria, Recent progress in precision machining and surface finishing of tungsten carbide hard composite coatings, Coatings 10(8) (2020) 731. https://doi.org/10.3390/coatings10080731 DOI: https://doi.org/10.3390/coatings10080731
[102] S. Zhang, J. Zhou, G. Hu, L. Wang, Y. Xu, Process characteristics of electrochemical discharge machining and hybrid methods: a review, The International Journal of Advanced Manu¬fac¬tu¬ring Technology 129(5) (2023) 1933-1963. http://dx.doi.org/10.1007/s00170-023-12452-4 DOI: https://doi.org/10.1007/s00170-023-12452-4
[103] L. Zhang, L. Kong, W. Lei, Q. Li, Review of electrochemical discharge machining technology for insulating hard and brittle materials, Journal of the Brazilian Society of Mechanical Sciences and Engineering 46(3) (2024) 143. http://dx.doi.org/10.1007/s40430-024-04739-8 DOI: https://doi.org/10.1007/s40430-024-04739-8
[104] M. Munjal, T. Prein, M. M. Ramadan, H. B. Smith, V. Venugopal, J. L. Rupp, K. J. Huang, Process cost analysis of performance challenges and their mitigations in sodium-ion battery cathode materials, Joule 9(5) (2025) 101871. https://doi.org/10.1016/j.joule.2025.101871 DOI: https://doi.org/10.1016/j.joule.2025.101871
[105] P. Jenis, T. Zhang, B. Ramasubramanian, S. Lin, P. R. Rayavarapu, J. Yu, S. Ramakrishna, Recent progress and hurdles in cathode recycling for Li-ion batteries, Circular Economy 3(2) (2024) 100087. https://doi.org/10.1016/j.cec.2024.100087 DOI: https://doi.org/10.1016/j.cec.2024.100087
[106] J. Xiao, C. Jiang, B. Wang, A review on dynamic recycling of electric vehicle battery: disas-sem¬bly and echelon utilization, Batteries 9(1) (2023) 57. https://doi.org/10.3390/batteries9010057 DOI: https://doi.org/10.3390/batteries9010057
[107] Y. Liu, P. Ouyang, Z. Zhang, H. Zhu, X. Chen, Y. Wang, J. Lu, Developments, challenges and future trends in advanced sustainable machining technologies for preparing array micro-holes, Nanoscale 16(43) (2024) 19938-19969. https://doi.org/10.1039/D4NR02910K DOI: https://doi.org/10.1039/D4NR02910K
[108] M. Sun, E. Toyserkani, A Novel Hybrid Ultrasound Abrasive-Driven Electrochemical Surface Finishing Technique for Additively Manufactured Ti6Al4V Parts, Inventions 9(2) (2024) 45. https://doi.org/10.3390/inventions9020045 DOI: https://doi.org/10.3390/inventions9020045
[109] M. Asmael, A. Memarzadeh, A review on recent achievements and challenges in electrochemical machining of tungsten carbide, Archives of Advanced Engineering Science 2(1) (2024) 1-23. https://doi.org/10.47852/bonviewAAES3202915 DOI: https://doi.org/10.47852/bonviewAAES3202915
[110] V. Subburam, S. Ramesh, L.I Freitas, Optimization and effect analysis of sustainable micro electrochemical machining using organic electrolyte, In Futuristic Trends in Intelligent Manufacturing: Optimization and Intelligence in Manufacturing, Springer International Publishing, 2021, 33-46. http://dx.doi.org/10.1007/978-3-030-70009-6_4 DOI: https://doi.org/10.1007/978-3-030-70009-6_4
[111] A. Speidel, J. Mitchell-Smith, D. A. Walsh, M. Hirsch, A. Clare, Electrolyte jet machining of titanium alloys using novel electrolyte solutions, Procedia CIRP 42 (2016) 367-372. http://dx.doi.org/10.1016/j.procir.2016.02.200 DOI: https://doi.org/10.1016/j.procir.2016.02.200
[112] R. K. Upadhyay, A. Kumar, P. . Srivastava, High rate anodic dissolution of stainless steel 316 (SS316) using nano zero valent iron as reducing agent, Journal of Applied Science and Engineering 19(1) (2016) 47-52. http://dx.doi.org/10.6180/jase.2016.19.1.06
[113] R. K. Upadhyay, A. K. Chakraborty, S. S. Majhi, A. C. Singh, B. Kumar, N. Yadav, Influences of redox electrolyte containing AuNPs on microscopic surface structure, material removal and surface roughness of 20MnCr5 steel alloy during electrochemical machining, Surface Science and Technology 3(1) (2025) 11. https://doi.org/10.1007/s44251-025-00074-9 DOI: https://doi.org/10.1007/s44251-025-00074-9
[114] R. K. Upadhyay, S. S. Majhi, S.S. Mahapatra, N. Yadav, A. K. Chakraborty, A. C. Singh, B. Kumar, A comparative study on material removal rate and surface roughness during electrochemical machining of 100Cr6 steel in oxidizing and reducing electrolytic environments. Proceedings of the Institution of Mechanical Engineers E (2025) 09544089251316751. https://doi.org/10.1177/09544089251316751 DOI: https://doi.org/10.1177/09544089251316751
[115] N. Besekar, B. Bhattacharyya, Electrochemical Characterization and Micromachining of Nitinol SMA by WECM Using Citric Acid Mixed H2SO4 Electrolyte, ECS Advances 2(3) (2023) 032501. https://doi.org/10.1149/2754-2734/acf947 DOI: https://doi.org/10.1149/2754-2734/acf947
[116] A. Sethi, B. R. Acharya, P. Saha, P. Study of the electrochemical dissolution behavior of Nitinol shape memory alloy in different electrolytes for micro ECM process, The International Journal of Advanced Manufacturing Technology 121(9) (2022) 7019-7035. http://dx.doi.org/10.21203/rs.3.rs-1077024/v1 DOI: https://doi.org/10.1007/s00170-022-09802-z
[117] S. Ayyappan, K. Sivakumar, Investigation of electrochemical machining characteristics of 20MnCr5 alloy steel using potassium dichromate mixed aqueous NaCl electrolyte and optimization of process parameters, Proceedings of the Institution of Mechanical Engineers, Part B: Journal of Engineering Manufacture 229(11) (2015) 1984-1996. https://doi.org/10.1177/0954405414542136 DOI: https://doi.org/10.1177/0954405414542136
[118] S. Ayyappan, K. Sivakumar, Enhancing the performance of electrochemical machining of 20MnCr5 alloy steel and optimization of process parameters by PSO-DF optimizer, The International Journal of Advanced Manufacturing Technology 82 (2016) 2053-2064. https://doi.org/10.1007/s00170-015-7511-6 DOI: https://doi.org/10.1007/s00170-015-7511-6
[119] A. Dvivedi, P. Kumar, Computational modelling and experimental investigation of micro-electrochemical discharge machining by controlling the electrolyte temperature, Journal of Micromechanics and Microengineering 34(3) (2024) 035001. http://dx.doi.org/10.1088/1361-6439/ad2089 DOI: https://doi.org/10.1088/1361-6439/ad2089
[120] X. Cao, Y. He, S. Wang, Numerical simulation and experimental study on micromilling-assisted electrochemical machining, International Journal of Electrochemical Science 20(3) (2025) 100934. https://doi.org/10.1016/j.ijoes.2025.100934 DOI: https://doi.org/10.1016/j.ijoes.2025.100934
[121] X. Zhou, Y. Jiang, Y. He, H. Guo, W. Gan, B. Xu, Multi-physical field simulation and experimental verification of electrochemical machining of curved holes, International Journal of Electrochemical Science 18(7) (2023) 100193. https://doi.org/10.1016/j.ijoes.2023.100193 DOI: https://doi.org/10.1016/j.ijoes.2023.100193
[122] M. Zhang, M. Chouchane, S.A. Shojaee, B. Winiarski, Z. Liu, L. Li, Y.S. Meng, Coupling of multi¬scale imaging analysis and computational modeling for understanding thick cathode degra¬dation mechanisms, Joule 7(1) (2023) 201-220. https://doi.org/10.1016/j.joule.2022.12.001 DOI: https://doi.org/10.1016/j.joule.2022.12.001
[123] S. D. Nagarale, B. P. Patil, Accelerating AI‐Based Battery Management System’s SOC and SOH on FPGA, Applied Computational Intelligence and Soft Computing 2023(1) (2023) 2060808. https://doi.org/10.1155/2023/2060808 DOI: https://doi.org/10.1155/2023/2060808
[124] W. Cao, D. Wang, G. Cui, J. Zhang, D. Zhu, Improvement on the machining accuracy of titanium alloy casing during counter-rotating electrochemical machining by using an insulation coating, Surface and Coatings Technology 443 (2022) 128585. https://doi.org/10.1016/j.surfcoat.2022.128585 DOI: https://doi.org/10.1016/j.surfcoat.2022.128585
[125] A. V. Ajay, S. S. Nair, S. Mohan, Y. Vaisakh, Investigation on the Influence of Nano Structured Zirconia Coating on the Corrosion Inhibition of SS 304 Stainless Steel, in Lecture Notes on Multidisciplinary Industrial Engineering (LNMUINEN), K. Antony, L. Davim, Eds, Advanced Manufacturing and Materials Science (2018) 203-212. http://dx.doi.org/10.1007/978-3-319-76276-0_20 DOI: https://doi.org/10.1007/978-3-319-76276-0_20
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Ritesh Kumar Upadhyay

This work is licensed under a Creative Commons Attribution 4.0 International License.


