Pre/post electron transfer regioselectivity at glycine modified graphene electrode interface for voltammetric sensing applications

Original scientific paper

Authors

  • Gururaj Kudur Jayaprakash Laboratory of Quantum Electrochemistry, School of Advanced Chemical Sciences, Shoolini University, Bajhol, Himachal Pradesh, 173229, India and Department of Chemistry, Nitte Meenakshi Institute of Technology, Bangalore, Karnataka, 560064, India https://orcid.org/0000-0003-0681-7815
  • Roberto Flores-Moreno Departamento de Química, Universidad Guadalajara,Blvd. Marcelino García Barragán 1421, Guadalajara, Jalisco, C.P. 44430, México https://orcid.org/0000-0001-5060-1363
  • Bahaddurghatta Eshwaraswamy Kumara Swamy Department of P.G. Studies and Research in Industrial Chemistry, Kuvempu University, Shankaraghatta -577451, Shimoga, Karnataka, India https://orcid.org/0000-0002-2433-0739
  • Kaustubha Mohanty Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati, 781039, India https://orcid.org/0000-0001-9810-9562
  • Pravesh Dhiman Medical Oncology Cell, Department of Radiotherapy and Oncology, IGMC, Shimla, 171001, Himachal Pradesh, India https://orcid.org/0000-0002-2490-6240

DOI:

https://doi.org/10.5599/jese.1438

Keywords:

Redox reaction, density functional theory, frontier molecular orbitals, Fukui analysis
Graphical Abstract

Abstract

In the last few years, glycine (GL) showed good experimental evidence as an electron transfer (ET) mediator at the carbon (in particular graphene (GR)) interface. However, ET properties of GL modified GR interface are still not known completely. These can be achieved using density functional theory-based models. Modelling of modified carbon electrode interfaces is essential in electroanalytical chemistry to get insights into their electronic and redox properties. Here we have modelled glycine modified graphene interface to find out its interfacial redox ET properties. Conceptual density functional theory concepts like frontier molecular orbital (FMO) theory and analytical Fukui functions were utilized to predict the ET sites on the modified graphene surface. It is shown that at the glycine-modified graphene interface, amine groups act as additional oxidation sites and carboxylic acid groups as additional reduction sites. Therefore, glycine acts as an ET mediator at the graphene-based electrode interface. The obtained results are well supported by previously published experimental reports.

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Published

23-08-2022

How to Cite

Jayaprakash, G. K., Flores-Moreno, R. ., Kumara Swamy, B. E. ., Mohanty, K. ., & Dhiman, P. (2022). Pre/post electron transfer regioselectivity at glycine modified graphene electrode interface for voltammetric sensing applications: Original scientific paper. Journal of Electrochemical Science and Engineering, 12(5), 1001–1008. https://doi.org/10.5599/jese.1438

Issue

Vol. 12 No. 5 (2022)

Section

Electrochemical Science

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