Exploration of the effect of Zn-MgO-UPP coating on hardness, corrosion resistance and microstructure properties of mild steel

Original scientific paper

Authors

  • Itopa Godwin Akande Department of Mechanical Engineering, Bells University of Technology, P.M.B. 1015, Ota, Ogun State, Nigeria https://orcid.org/0000-0002-6807-8539
  • Ojo Sunday Isaac Fayomi Department of Mechanical Engineering, Bells University of Technology, P.M.B. 1015, Ota, Ogun State, Nigeria
  • Bassey Jonah Akpan Department of Mechanical Engineering, Bells University of Technology, P.M.B. 1015, Ota, Ogun State, Nigeria https://orcid.org/0000-0003-3311-2095
  • Olajide Abraham Aogo Department of Research and Development Unit, Standard Connections Limited, Nigeria and Department of Mechanical Engineering, University of Ibadan, Ibadan, Oyo State, Nigeria https://orcid.org/0000-0003-0582-8715
  • Patrick Nwanne Onwordi Department of Mechanical Engineering, Bells University of Technology, P.M.B. 1015, Ota, Ogun State, Nigeria https://orcid.org/0000-0003-1849-6182

DOI:

https://doi.org/10.5599/jese.1311

Keywords:

SEM, XRD, passivation, composite, homogeneity

Abstract

This paper investigated the effect of unripe plantain peel (UPP) nanoparticles reinforced Zn-MgO composite coating on the hardness, anti-corrosion and microstructure properties of mild steel. The anti-corrosion characteristics of the coatings were examined using the potentiodynamic polarization method, employing 3.65 % NaCl solution as the test medium. The hardness of the coatings was studied employing the Brinell hardness technique, while the microstructure characteristics were examined using XRD and SEM/EDS. The results of the study revealed that the as-received mild steel sample exhibited the corrosion rate and hardness value of 8.6272 mm year-1 and 136.8 kgf mm-2, respectively, while the Zn-MgO co­ated mild steel sample exhibited a corrosion rate and hardness value of 3.6362 mm year-1 and 42.5 kgf mm-2, respectively. The optimal performing Zn-MgO-UPP coated mild steel sample (sample coated with 20 g L-1 of MgO and 6 g L-1 of UPP) exhibited a corrosion rate and hardness value of 0.8317 mm year-1 and 245.8 kgf mm-2, respectively. The corrosion rate and hardness value of the Zn-20MgO-6UPP coated mild steel sample indicated that the UPP nanoparticles further improved the passivating and strengthening ability of Zn-MgO coating. Moreover, the XRD profile of the coatings possessed high intensities, which indi­cat­ed that the coatings exhibit microstructural and chemical homogeneity, high stability and good texture. It was observed on the SEM micrographs that the Zn-MgO-UPP coating exhi­bited a more refined microstructure compared to the Zn-MgO coating, indicating the grain refining tendency of the UPP nanoparticles. The EDS further indicated the presence of essential and dispersion strengthening elements in the coatings.

Downloads

Download data is not yet available.

References

E. Ohaeri, U. Eduok, J. Szpunar, International Journal of Hydrogen Energy 43 (2018) 14584-14617. https://doi.org/10.1016/j.ijhydene.2018.06.064 DOI: https://doi.org/10.1016/j.ijhydene.2018.06.064

M. Shivakumar, M. S. Dharmaprakash, S. Manjappa, K. L. Nagashree, Portugaliae Electrochimica Acta 35 (2017) 351-359. http://dx.doi.org/10.4152/pea.201706351 DOI: https://doi.org/10.4152/pea.201706351

M. Murmu, S. K. Saha, N. C. Murmu, P. Banerjee, Journal of Molecular Liquids 278 (2019) 521-535. https://doi.org/10.1016/j.molliq.2019.01.066 DOI: https://doi.org/10.1016/j.molliq.2019.01.066

O. S. I. Fayomi, I. G. Akande, D. E. Ighravwe, D. O. Aikhuele, Key Engineering Materials 886 (2021) 119-125. https://doi.org/10.4028/www.scientific.net/KEM.886.119 DOI: https://doi.org/10.4028/www.scientific.net/KEM.886.119

R. A. Rahman Rashid, M. A. Javed, C. Barr, S. Palanisamy, N. Matthews, M. S. Dargusch, International Journal of Advanced Manufacturing Technology 117 (2021) 2949-2958. https:/doi.org/10.1007/s00170-021-07886-7 DOI: https://doi.org/10.1007/s00170-021-07886-7

W. Wu, Q. Wang, L. Yang, Z. Liu, X. Li, Y. Li, Journal of Materials Research and Technology 9 (2020) 12976-12995. https://doi.org/10.1016/j.jmrt.2020.09.033 DOI: https://doi.org/10.1016/j.jmrt.2020.09.033

T. O. Olugbade, Analytical Letters 54 (2021) 1055-1067. https://doi.org/10.1080/00032719.2020.1793994 DOI: https://doi.org/10.1080/00032719.2020.1793994

R. Wang, R. A. Shenoi, A. Sobey, Journal of Constructional Steel Research 143 (2018) 331-342. https://doi.org/10.1016/j.jcsr.2018.01.014 DOI: https://doi.org/10.1016/j.jcsr.2018.01.014

J. C. Kurth, P. D. Krauss, S. W. Foster, Transportation Research Record 2673 (2019) 2-14. https://doi.org/10.1177/0361198119855333 DOI: https://doi.org/10.1177/0361198119855333

O. S. I. Fayomi, I. G. Akande, C. Ofo, Key Engineering Materials 886 (2021) 159-167. https://doi.org/10.4028/www.scientific.net/KEM.886.159 DOI: https://doi.org/10.4028/www.scientific.net/KEM.886.159

G. Bahlakeh, B. Ramezanzadeh, M. Ramezanzadeh, Journal of Cleaner Production 210 (2019) 872-886. https://doi.org/10.1016/j.jclepro.2018.11.089 DOI: https://doi.org/10.1016/j.jclepro.2018.11.089

A. Arul, S. Sivagnanam, A. Dey, O. Mukherjee, S. Ghosh, P. Das, RSC Advances 10 (2020) 13420-13429. https://doi.org/10.1039/C9RA10018K DOI: https://doi.org/10.1039/C9RA10018K

M. A. Fusco, C. J. Oldham, G. N. Parsons, Materials 12 (2019) 672. https://doi.org/10.3390/ma12040672 DOI: https://doi.org/10.3390/ma12040672

M. Shourgeshty, M. Aliofkhazraei, A. Karimzadeh, Surface Engineering 35 (2019) 167-176. https://doi.org/10.1080/02670844.2018.1432172 DOI: https://doi.org/10.1080/02670844.2018.1432172

M. Alizadeh, H. Safaei, Applied Surface Science 456 (2018) 195-203. https://doi.org/10.1016/j.apsusc.2018.06.095 DOI: https://doi.org/10.1016/j.apsusc.2018.06.095

O. S. I. Fayomi, G. A. Oluwadare, O. B. Fakehinde, I. G. Akande, W. Nwachia, U. Oziegbe, A. J. Russell, International Journal of Advanced Manufacturing Technology 103 (2019) 2621-2625. https://doi.org/10.1007/s00170-019-03714-1 DOI: https://doi.org/10.1007/s00170-019-03714-1

A. Lelevic, F. C. Walsh, Surface and Coatings Technology 369 (2019) 198-220. https://doi.org/10.1016/j.surfcoat.2019.03.055 DOI: https://doi.org/10.1016/j.surfcoat.2019.03.055

R. Manivannan, S. N. Victoria, Solar Energy 173 (2018) 1144-1157. https://doi.org/10.1016/j.solener.2018.08.057 DOI: https://doi.org/10.1016/j.solener.2018.08.057

A. D. Torkamani, M. Velashjerdi, A. Abbas, M. Bolourchi, P. Maji, Journal of Composites and Compounds 3 (2021) 106-113. https://doi.org/10.52547/jcc.3.2.4 DOI: https://doi.org/10.52547/jcc.3.2.4

R. Bhat, A. C. Hegde, J. Electrochem. Sci. Eng. 9(1) (2019) 9-16. https://doi.org/10.5599/jese.565 DOI: https://doi.org/10.5599/jese.565

R. A. Jassim, M. S. Sando, A. M. Farhan, Baghdad Science Journal 19 (2022) 347-354. https://doi.org/10.21123/bsj.2022.19.2.0347 DOI: https://doi.org/10.21123/bsj.2022.19.2.0347

N. LeBozec, D. Thierry, D. Persson, C. K. Riener, G. Luckeneder, Surface and Coatings Technology 374 (2019) 897-909. https://doi.org/10.1016/j.surfcoat.2019.06.052 DOI: https://doi.org/10.1016/j.surfcoat.2019.06.052

M. Riđošić, E. García-Lecina, A. Salicio-Paz, J. Bajat, Transactions of the IMF 98 (2020) 114-120. https://doi.org/10.1080/00202967.2020.1748390 DOI: https://doi.org/10.1080/00202967.2020.1748390

O. S. I. Fayomi, O. O. Joseph, I. G. Akande, C. K. Ohiri, K. O. Enechi, N. E. Udoye, Journal of Alloys and Compounds 783 (2019) 246-255. https://doi.org/10.1016/j.jallcom.2018.12.312 DOI: https://doi.org/10.1016/j.jallcom.2018.12.312

O. A. Adetayo, O. Jubril, Fuoye Journal of Engineering and Technology 4 (2019)145-148. https://doi.org/10.46792/FUOYEJET.V4I1.318 DOI: https://doi.org/10.46792/fuoyejet.v4i1.318

J. G. Thakare, C. Pandey, M. M. Mahapatra, R. S. Mulik, Metals and Materials International 27 (2021) 1947-1968. https://doi.org/10.1007/s12540-020-00705-w DOI: https://doi.org/10.1007/s12540-020-00705-w

V. Kumar, K. Balasubramanian, Progress in Organic Coatings 90 (2016) 54-82. https://doi.org/10.1016/j.porgcoat.2015.09.019 DOI: https://doi.org/10.1016/j.porgcoat.2015.09.019

S. G. Croll, Progress in Organic Coatings 148 (2020) 105847. https://doi.org/10.1016/j.porgcoat.2020.105847 DOI: https://doi.org/10.1016/j.porgcoat.2020.105847

M. Islam, M. R. Azhar, N. Fredj, T. D. Burleigh, O. R. Oloyede, A. A. Almajid, S. I. Shah, Surface and Coatings Technology 261 (2015) 141-148. https://doi.org/10.1016/j.surfcoat.2014.11.044 DOI: https://doi.org/10.1016/j.surfcoat.2014.11.044

O. S. I. Fayomi, I. G. Akande, A. P. I. Popoola, Journal of Bio-and Tribo-Corrosion 4 (2018) 73. https://doi.org/10.1007/s40735-018-0192-6 DOI: https://doi.org/10.1007/s40735-018-0192-6

A. Buyuksagis, A. T. Baydır, M. Dilek, Protection of Metals and Physical Chemistry of Surfaces 57 (2021) 211-221. http://dx.doi.org/10.1134/S2070205120060076 DOI: https://doi.org/10.1134/S2070205120060076

R. Zandi Zand, V. Flexer, M. De Keersmaecker, K. Verbeken, M. Adriaens, International Journal of Electrochemical Science 10 (2015) 997-1014. http://hdl.handle.net/1854/LU-5775729 DOI: https://doi.org/10.1016/S1452-3981(23)05051-4

L. Pan, W. Ding, W. Ma, J. Hu, X. Pang, F. Wang, J. Tao, Materials & Design 160 (2018) 1106-1116. https://doi.org/10.1016/j.matdes.2018.10.034 DOI: https://doi.org/10.1016/j.matdes.2018.10.034

T. S. Hamidon, M. H. Hussin, Progress in Organic Coatings 140 (2020) 105478. https://doi.org/10.1016/j.porgcoat.2019.105478 DOI: https://doi.org/10.1016/j.porgcoat.2019.105478

I. G. Akande, O. O. Oluwole, O. S. I. Fayomi, Defence Technology 15 (2019) 526-532. https://doi.org/10.1016/j.dt.2018.11.001 DOI: https://doi.org/10.1016/j.dt.2018.11.001

C. Y. Ma, D. Q. Zhao, F. F. Xia, H. Xia, T. Williams, H. Y. Xing, Ceramics International 46 (2020) 6115-6123. https://doi.org/10.1016/j.ceramint.2019.11.075 DOI: https://doi.org/10.1016/j.ceramint.2019.11.075

M. J. Benoit, I. G. Ogunsanya, S. Winkler, M. J. Worswick, M. A. Wells, C. M. Hansson, Journal of Materials Engineering and Performance 30 (2021) 2876-2889. https://doi.org/10.1007/s11665-021-05616-4 DOI: https://doi.org/10.1007/s11665-021-05616-4

K. Brandenburg, D. Hornbach, P. Prevey, N. Jayaraman, Analysis and Prevention 21 (2021) 1002–1010. https://doi.org/10.1007/s11668-021-01146-2 DOI: https://doi.org/10.1007/s11668-021-01146-2

A. Singh, G. Singh, V. Chawla, Journal of the Mechanical Behavior of Biomedical Materials 85 (2018) 20-36. https://doi.org/10.1016/j.jmbbm.2018.05.030 DOI: https://doi.org/10.1016/j.jmbbm.2018.05.030

N. Jager, M. Meindlhumer, S. Spor, H. Hruby, J. Julin, A. Stark, R. Daniel, Acta Materialia 186 (2020) 545-554. https://doi.org/10.1016/j.actamat.2020.01.026 DOI: https://doi.org/10.1016/j.actamat.2020.01.026

L. Wang, S. Xing, Z. Shen, H. Liu, C. Jiang, V. Ji, Y. Zhao, Journal of Materials Science & Technology 105 (2022) 182-193. https://doi.org/10.1016/j.jmst.2021.08.002 DOI: https://doi.org/10.1016/j.jmst.2021.08.002

A. Sadeghzadeh-Attar, G. Ayubikia, M. Ehteshamzadeh, Surface and Coatings Technology 307 (2016) 837-848. https://doi.org/10.1016/j.surfcoat.2016.10.026 DOI: https://doi.org/10.1016/j.surfcoat.2016.10.026

S. Tikale, K. N. Prabhu, Journal of Materials Science: Materials in Electronics 32 (2021) 2865-2886. https://doi.org/10.1007/s10854-020-05040-9 DOI: https://doi.org/10.1007/s10854-020-05040-9

K. Alipour, F. Nasirpouri, Journal of the Electrochemical Society 166 (2019) D1-D9. https://doi.org/10.1149/2.0191902jes DOI: https://doi.org/10.1149/2.0191902jes

A. A. Ayoola, O. S. I. Fayomi A. P. I. Popoola, Defence Technology 15 (2019) 106-110. https://doi.org/10.1016/j.dt.2018.04.008 DOI: https://doi.org/10.1016/j.dt.2018.04.008

M. Sivapragash, P. Kumaradhas, B. S. J. Retnam, X. F. Joseph, U. T. S. Pillai, Materials & Design 90 (2016) 713-722. https://doi.org/10.1016/j.matdes.2015.11.027 DOI: https://doi.org/10.1016/j.matdes.2015.11.027

I. Milosev, G. S. Frankel, Journal of the Electrochemical Society 165 (2018) C127-C144. https://doi.org/10.1149/2.0371803jes DOI: https://doi.org/10.1149/2.0371803jes

X. Li, Y. Feng, B. Liu, D. Yi, X. Yang, W. Zhang, P. Bai, Journal of Alloys and Compounds 788 (2019) 485-494. https://doi.org/10.1016/j.jallcom.2019.02.223 DOI: https://doi.org/10.1016/j.jallcom.2019.02.223

J. Wang, H. Yang, H. Huang, J. Ruan, S. Ji, Journal of Alloys and Compounds 798 (2019) 576-586. https://doi.org/10.1016/j.jallcom.2019.05.208 DOI: https://doi.org/10.1016/j.jallcom.2019.05.208

T. Han, J. Li, N. Zhao, C. He, Carbon 159 (2020) 311-323. https://doi.org/10.1016/j.carbon.2019.12.029 DOI: https://doi.org/10.1016/j.carbon.2019.12.029

Downloads

Published

04-05-2022

Issue

Section

Electrodeposition and coatings

How to Cite

Exploration of the effect of Zn-MgO-UPP coating on hardness, corrosion resistance and microstructure properties of mild steel: Original scientific paper. (2022). Journal of Electrochemical Science and Engineering, 12(5), 829-840. https://doi.org/10.5599/jese.1311