J. Electrochem. Sci. Eng.  

Simulation of square wave voltammetry of three electrode reactions coupled by two reversible chemical reactions

Milivoj Lovrić

Abstract


Three fast and reversible electrode reactions that are connected by two reversible chemical reactions that are permanently in the equilibrium are analysed theoretically for square wave voltammetry. The dependence of peak potentials on the dimensionless equilibrium constants of chemical reactions is calculated. The influence of the basic thermodynamic parameters on the square wave voltammetric responses is analysed.


Keywords


ECECE mechanism; equilibrium conditions; voltammetry; theory

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DOI: http://dx.doi.org/10.5599/jese.409

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